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- W1987367284 abstract "Abstract The reactions of O(21D2) with the halomethanes CFCl3, CF2Cl2, CF3Cl, CF2HCl, CFHCl2 and CF3Br have been studied using flash photolysis with kinetic spectroscopy (O(21D2) atoms were generated by photolysis of O3 or N2O in the ultraviolet). Formation of ClO has been observed and lower limits for the branching ratio into the channel relative to the total cross section for removal of O(21D2) were determined as 0.39, 0.47, 0.39, 0.27 and 0.36 for the molecules CF3Cl, CF2Cl2, CFCl3, CF2HCl and CFHCl2, respectively. The secondary yields of ClO following the reaction of CFxCl3−x radicals with O2 are also reported. The reaction of O(21D2) with CF3Br is shown to yield BrO as a primary product. The photolysis of CCl3Br in the presence of O2 is also shown to yield BrO, but in this case via secondary reactions." @default.
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- W1987367284 date "1977-01-01" @default.
- W1987367284 modified "2023-09-27" @default.
- W1987367284 title "Reaction of O(21D2) with halomethanes" @default.
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- W1987367284 doi "https://doi.org/10.1016/0047-2670(77)87003-2" @default.
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