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- W1987384087 abstract "A review is given of a selection of papers published in the past year in this rapidly expanding field. Such papers may be divided into four groups: (i) those in which ring-closing metathesis (RCM) has been used as a key step in the total synthesis of a natural product: (R)-(+)-lasiodiplodin, dactylol, (−)-stemoamide, and epothilone A; (ii) those in which RCM has been used to make a sub-unit of a natural product: the marine toxins brevetoxin B, brevetoxin A, and maitotoxin; (iii) those in which RCM has been used to make compounds of known biological activity: fluvirucin B1 (Sch 38516); (iv) those in which metathesis reactions have been used to make compounds of potential synthetic importance: crown ethers, aza sugars (polyhydroxylated pyrrolidines), β-lactams, chromenes, and aminoacids. The catalysts used have been one of the following four metal carbene complexes: the Schrock catalyst Mo(CHCMe2Ph)(NC6H3-2,6-i-Pr2)[OCMe(CF3)2]2; the Grubbs catalysts Ru(CHCHCPh2)Cl2(PCy3)2 and Ru(CHPh)Cl2(PCy3)2, where Cy=cyclohexyl; and the Tebbe reagent which behaves as Ti(CH2)Cp2, where Cp=cyclopentadienyl. In this paper these are denoted by Mo-1, Ru-1, Ru-2, and Ti-1, respectively. Ti-1 is especially useful for effecting RCM by the carbonyl–olefination reaction, while the RCM of enynes, catalyzed by Ru-2, is another valuable metathesis reaction." @default.
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- W1987384087 date "1998-07-01" @default.
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- W1987384087 title "Some recent applications of olefin metathesis in organic synthesis: A review" @default.
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- W1987384087 doi "https://doi.org/10.1016/s1381-1169(97)00249-5" @default.
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