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- W1987394869 abstract "Reaction of [Fe(acac)3], (NEt4)OAc and N(CH2CH2SH)3 in MeCN in the presence of NO gives (NEt4)[Fe(NS3)(NO)] (1) [where NS3 = N(CH2CH2S)3]. Complex 1 reacts with metal chloride solvates, giving insoluble compounds of stoichiometry MFe2(NO)2(NS3)2, probably having the structure [M{Fe(NS3)(NO)}2-S,S′] [M = Fe (2), Co (3), Ni (4), Cu (5)], the nitrosyl analogues of known structurally characterised carbonyl compounds. 1 also reacts with HBF4·Et2O, giving the tetranuclear complex [{Fe(NO)2{Fe(NS3)}-S,S′}2-S,S′] (6), which adds small molecules, L, giving the binuclear complexes [Fe(NO)2{Fe(NS3)(L)}-S,S′] [L = CO (7), CNMe (8), NO (9), CN− (10)]. Complexes 6–9 are more conveniently prepared by treatment of [Fe(NS3)(L)]− precursors with half an equivalent of [{Fe(NO)2}2(μ-I)2]. Reaction of (NEt4)[Co(NS3)(CN)] with half an equivalent of [{Fe(NO)2}2(μ-I)2] gives [Fe(NO)2{Co(NS3)(CN)}-S,S′] (11). Treatment of the [Fe(NS3)L] precursors used to make 7–9 with one equivalent of [{Fe(NO)2}2(μ-I)2] gives another series of complexes, [{Fe(NO)2I}-S{Fe(NS3)(L)}-S′,S″{Fe(NO)2}] [L = CO (12), CNMe (13), NO (14)]. Products were characterised by microanalyses, IR and Mössbauer spectra; X-ray crystal structure determinations were carried out on 1, 6, 7, 9, 10, 13 and 14. Magnetic measurements at room temperature showed evidence of spin pairing in all the polynuclear complexes." @default.
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- W1987394869 date "2002-05-13" @default.
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- W1987394869 title "Mononuclear, binuclear, trinuclear and tetranuclear iron complexes of the N(CH2CH2S)33– (NS3) ligand with nitrosyl co-ligands" @default.
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- W1987394869 doi "https://doi.org/10.1039/b200694b" @default.
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