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- W1987395879 abstract "In the course of a systematic examination of the possible existence of intermetallic compounds of europium and ytterbium which can show anomalous valency behaviour, the binary phase diagram of the Eu-Pt system was studied by means of differential thermal analysis, X-ray analysis and metallographic analysis. Seven intermediate phases were found to exist: Eu9Pt; Eu5Pt2; Eu3Pt2; Eu5Pt4; EuPt2; Eu2Pt7; EuPt5. For most of these phases the crystal structures and lattice constants were determined. The valency behaviour in these phases together with those formed in the Yb-Pt system was studied by means of magnetic measurements and analysis of lattice dimensions, atomic volumes and ionic radii. The conclusion is that europium and ytterbium can form intermetallic phases with platinum, containing divalent or trivalent ions. Moreover, whereas europium in the platinum-rich side of the EuPt2 solid solution, and perhaps in Eu2Pt7, appears to give rise to “mixed valency states”, ytterbium in Yb2Pt, Yb5Pt3 and Yb5Pt4 shows “fluctuating valency” behaviour." @default.
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- W1987395879 date "1981-08-01" @default.
- W1987395879 modified "2023-10-16" @default.
- W1987395879 title "The phase diagram of the Eu-Pt system and the valency behaviour of europium and ytterbium intermetallics with platinum" @default.
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- W1987395879 doi "https://doi.org/10.1016/0022-5088(81)90103-x" @default.
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