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- W1987397466 abstract "Previous attempts to synthesize boracyclanes in the medium-ring range (9-, 10-, 11-, and 12-ring members) via cyclic hydroboration of α,ω-dienes have failed. However, their synthesis via the sequential one-carbon homologation of B-methoxyboracyclanes has been achieved utilizing the successive reaction of B-methoxyboracyclanes with in situ generated (chloromethyl)lithium (LiCH2Cl): MeOB(CH2)5 → MeOB(CH2)6 → MeOB(CH2)7 → MeOB(CH2)8 → MeOB(CH2)9 → MeOB(CH2)10 → MeOB(CH2)11. The yields achieved are in the range of 75–85%. In each case the products are identified by conversion via the DCME reaction into the known cycloalkanones. This development provides the first entry into boracyclanes of the strained medium ring range." @default.
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- W1987397466 date "1990-01-01" @default.
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- W1987397466 title "Organoboranes. 52. The successful ring enlargement of boracyclanes via sequential one-carbon homologation: The first synthesis of boracyclanes in the strained medium-ring range" @default.
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- W1987397466 doi "https://doi.org/10.1002/hc.520010112" @default.
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