FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1987399855> ?p ?o ?g. }

• W1987399855 endingPage "144" @default.
• W1987399855 startingPage "71" @default.
• W1987399855 abstract "Several transition-metal oxides with formula MxTOm exhibit a wide phase field and high electrical conductivity. These “bronzes” consist of a (TOm)n covalent network into which are inserted xM+ (or M2+ or M3+) cations that donate their outer electrons to the transition-metal array to give a mean formal valence per T atom of +(2m − x). The conducting electrons may be either delocalized over the covalent network or localized at discrete T atoms. Best known are the tungsten bronzes MxWO3, in which the donor M cations occupy tunnels of square, pentagonal, or hexagonal crosssection within a WO3 network of corner-shared octahedra. Which bronze structure (cubic, tetragonal or hexagonal network) is stabilized depends upon the size of the M cations and their concentration. With low values of x, some of the WO3 octahedra are irregular, characteristic of the antiferroelectric distortions found in WO3, and the compounds (or two-phase mixtures) are semiconducting. The cubic, tetragonal and hexagonal bronzes, which occur for larger values of x, are all metallic. The molybdenum bronzes MxMoO3, though generally analogous to the tungsten compounds, appear to be metastable under normal conditions. The vanadium brozes, on the other hand, form quite a different structural family. In general, the vanadium ions have an irregular anion coordination that is intermediate between a triangular bipyramid and a regular octahedron. Most familiar are the MxV2O5 series, but other chemical formulae are possible, several with a double mechanism of nonstoichiometry. Mixed vanadium-molybdenum and vanadium-tungsten families have also been studied. Titanium and manganese bronzes, which are derived from the rutile structure, also exist. All available physical data for these systems are presented, and the electronic properties are discussed in terms of specific structural features." @default.
• W1987399855 created "2016-06-24" @default.
• W1987399855 creator A5014027600 @default.
• W1987399855 date "1971-01-01" @default.
• W1987399855 modified "2023-09-23" @default.
• W1987399855 title "Les bronzes oxygénés" @default.
• W1987399855 cites W1609606734 @default.
• W1987399855 cites W1965187499 @default.
• W1987399855 cites W1968847235 @default.
• W1987399855 cites W1970189230 @default.
• W1987399855 cites W1971786830 @default.
• W1987399855 cites W1974092854 @default.
• W1987399855 cites W1987377813 @default.
• W1987399855 cites W1987418338 @default.
• W1987399855 cites W1991617765 @default.
• W1987399855 cites W1992050426 @default.
• W1987399855 cites W1998693884 @default.
• W1987399855 cites W1999337675 @default.
• W1987399855 cites W2001255736 @default.
• W1987399855 cites W2012901290 @default.
• W1987399855 cites W2015847925 @default.
• W1987399855 cites W2019530541 @default.
• W1987399855 cites W2021063096 @default.
• W1987399855 cites W2021339195 @default.
• W1987399855 cites W2028096143 @default.
• W1987399855 cites W2035118029 @default.
• W1987399855 cites W2036955274 @default.
• W1987399855 cites W2041330184 @default.
• W1987399855 cites W2047551824 @default.
• W1987399855 cites W2047769280 @default.
• W1987399855 cites W2050167279 @default.
• W1987399855 cites W2072038944 @default.
• W1987399855 cites W2072194495 @default.
• W1987399855 cites W2079802760 @default.
• W1987399855 cites W2082640309 @default.
• W1987399855 cites W2085070902 @default.
• W1987399855 cites W2091616408 @default.
• W1987399855 cites W2095223288 @default.
• W1987399855 cites W2099142392 @default.
• W1987399855 cites W2127497963 @default.
• W1987399855 cites W2148340150 @default.
• W1987399855 cites W2161483477 @default.
• W1987399855 cites W2315378416 @default.
• W1987399855 cites W2317132143 @default.
• W1987399855 cites W2319774475 @default.
• W1987399855 cites W2321532487 @default.
• W1987399855 cites W2326413971 @default.
• W1987399855 cites W2329758905 @default.
• W1987399855 cites W2329893455 @default.
• W1987399855 cites W2332243189 @default.
• W1987399855 cites W2335275297 @default.
• W1987399855 cites W2737735993 @default.
• W1987399855 doi "https://doi.org/10.1016/0079-6786(71)90017-3" @default.
• W1987399855 hasPublicationYear "1971" @default.
• W1987399855 type Work @default.
• W1987399855 sameAs 1987399855 @default.
• W1987399855 citedByCount "95" @default.
• W1987399855 countsByYear W19873998552012 @default.
• W1987399855 countsByYear W19873998552017 @default.
• W1987399855 countsByYear W19873998552018 @default.
• W1987399855 crossrefType "journal-article" @default.
• W1987399855 hasAuthorship W1987399855A5014027600 @default.
• W1987399855 hasConcept C106773901 @default.
• W1987399855 hasConcept C115624301 @default.
• W1987399855 hasConcept C121332964 @default.
• W1987399855 hasConcept C145148216 @default.
• W1987399855 hasConcept C147120987 @default.
• W1987399855 hasConcept C161790260 @default.
• W1987399855 hasConcept C168900304 @default.
• W1987399855 hasConcept C170751736 @default.
• W1987399855 hasConcept C178790620 @default.
• W1987399855 hasConcept C185592680 @default.
• W1987399855 hasConcept C191897082 @default.
• W1987399855 hasConcept C192562407 @default.
• W1987399855 hasConcept C198819137 @default.
• W1987399855 hasConcept C2778478046 @default.
• W1987399855 hasConcept C38649801 @default.
• W1987399855 hasConcept C504678139 @default.
• W1987399855 hasConcept C542268612 @default.
• W1987399855 hasConcept C544153396 @default.
• W1987399855 hasConcept C549387045 @default.
• W1987399855 hasConcept C55493867 @default.
• W1987399855 hasConcept C62520636 @default.
• W1987399855 hasConcept C70050531 @default.
• W1987399855 hasConcept C8010536 @default.
• W1987399855 hasConceptScore W1987399855C106773901 @default.
• W1987399855 hasConceptScore W1987399855C115624301 @default.
• W1987399855 hasConceptScore W1987399855C121332964 @default.
• W1987399855 hasConceptScore W1987399855C145148216 @default.
• W1987399855 hasConceptScore W1987399855C147120987 @default.
• W1987399855 hasConceptScore W1987399855C161790260 @default.
• W1987399855 hasConceptScore W1987399855C168900304 @default.
• W1987399855 hasConceptScore W1987399855C170751736 @default.
• W1987399855 hasConceptScore W1987399855C178790620 @default.
• W1987399855 hasConceptScore W1987399855C185592680 @default.
• W1987399855 hasConceptScore W1987399855C191897082 @default.
• W1987399855 hasConceptScore W1987399855C192562407 @default.
• W1987399855 hasConceptScore W1987399855C198819137 @default.

• next