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- W1987404688 abstract "Abstract The reactions of the cluster HRu 3 (CCBu t )(CO) 9 ( 1 ) with the bidentate ligands Ph 2 PCH 2 CH 2 EPh 2 (E = P, dppe; E = As, dppae), in the presence of Me 3 NO, give the complexes HRu 3 (CCBu t )(CO) 7 (Ph 2 PCH 2 CH 2 EPh 2 ), as two isomers, which have been separated by TLC. In the first isomer, the ligand chelates the ruthenium atom opposite to the bridging hydride (1,1-derivative), whereas, in the second, it bridges a hydride-free edge (1,2-derivative). In contrast the rather rigid diphosphine cis -Ph 2 PCHCHPPh 2 (c-dppet) gives only the 1,1-derivative. When chelating, the ligands do not show any significant fluxional behaviour, but when they are bridging there is interconvension between axial and equatorial positions." @default.
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- W1987404688 date "1989-11-01" @default.
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- W1987404688 title "Chelating and bridging behaviour of bidentate P,P or P,As ligands (LL) in HRu3(CCBut)(CO)7(LL) as indicated by 1H, 13C and 31P NMR spectroscopy" @default.
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- W1987404688 doi "https://doi.org/10.1016/0022-328x(89)85012-0" @default.
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