FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1987405424> ?p ?o ?g. }

• W1987405424 endingPage "1339" @default.
• W1987405424 startingPage "1339" @default.
• W1987405424 abstract "The LiMn1.5Ni0.5O4 spinel is an attractive cathode candidate for next generation lithium-ion batteries as it offers high power capability with an operating voltage of ∼4.7 V and a capacity of ∼135 mA h g−1. However, its commercialization is plagued by severe capacity fade, particularly at elevated temperatures, in full cells employing a graphite anode. This perspective article provides an overview of the recent developments on understanding various factors that influence the electrochemical performance of the high-voltage spinel cathodes. The factors include the degree of cation ordering, Mn3+ content, morphology, and surface planes/compositions in contact with the electrolyte, which are influenced by synthesis and annealing conditions as well as cation doping. For example, samples with a {111} family of surface planes show superior performance. Recent magnetic measurements and examination of discharge profiles below 3 V have become valuable to get a more precise measure of the degree of cation ordering. Also, surface modifications and electrolyte additives have shown marginal gains. Although acceptable performances have been obtained in half-cells with a metallic lithium anode, capacity fade is seen in full cells with a graphite anode due to metal dissolution at the high operating voltage of 4.7 V and Li+ consumption by the steadily forming solid–electrolyte interphase (SEI) layer promoted by Mn/Ni deposition on the graphite surface. Based on the current understanding, future directions are pointed out." @default.
• W1987405424 created "2016-06-24" @default.
• W1987405424 creator A5000018076 @default.
• W1987405424 creator A5062434800 @default.
• W1987405424 creator A5066705036 @default.
• W1987405424 date "2014-01-01" @default.
• W1987405424 modified "2023-10-14" @default.
• W1987405424 title "A perspective on the high-voltage LiMn1.5Ni0.5O4 spinel cathode for lithium-ion batteries" @default.
• W1987405424 cites W1505155732 @default.
• W1987405424 cites W1550595230 @default.
• W1987405424 cites W1566878912 @default.
• W1987405424 cites W1769213404 @default.
• W1987405424 cites W1773022274 @default.
• W1987405424 cites W1780160413 @default.
• W1987405424 cites W1811354186 @default.
• W1987405424 cites W1817347473 @default.
• W1987405424 cites W1963933784 @default.
• W1987405424 cites W1964229205 @default.
• W1987405424 cites W1964347618 @default.
• W1987405424 cites W1966318268 @default.
• W1987405424 cites W1968471782 @default.
• W1987405424 cites W1972977605 @default.
• W1987405424 cites W1973863287 @default.
• W1987405424 cites W1974160027 @default.
• W1987405424 cites W1980166452 @default.
• W1987405424 cites W1983059518 @default.
• W1987405424 cites W1984843020 @default.
• W1987405424 cites W1985700793 @default.
• W1987405424 cites W1994632670 @default.
• W1987405424 cites W1999278114 @default.
• W1987405424 cites W1999818232 @default.
• W1987405424 cites W2002412173 @default.
• W1987405424 cites W2004254424 @default.
• W1987405424 cites W2004428557 @default.
• W1987405424 cites W2006318126 @default.
• W1987405424 cites W2010475530 @default.
• W1987405424 cites W2014029234 @default.
• W1987405424 cites W2015727774 @default.
• W1987405424 cites W2016436135 @default.
• W1987405424 cites W2018998774 @default.
• W1987405424 cites W2019283480 @default.
• W1987405424 cites W2019291584 @default.
• W1987405424 cites W2020659412 @default.
• W1987405424 cites W2024942773 @default.
• W1987405424 cites W2028709462 @default.
• W1987405424 cites W2028909655 @default.
• W1987405424 cites W2034725576 @default.
• W1987405424 cites W2037104312 @default.
• W1987405424 cites W2039728017 @default.
• W1987405424 cites W2040552963 @default.
• W1987405424 cites W2041624346 @default.
• W1987405424 cites W2045075906 @default.
• W1987405424 cites W2045956283 @default.
• W1987405424 cites W2049860091 @default.
• W1987405424 cites W2050148122 @default.
• W1987405424 cites W2051318699 @default.
• W1987405424 cites W2052362608 @default.
• W1987405424 cites W2056129712 @default.
• W1987405424 cites W2061325091 @default.
• W1987405424 cites W2062048072 @default.
• W1987405424 cites W2062055782 @default.
• W1987405424 cites W2062697901 @default.
• W1987405424 cites W2064717378 @default.
• W1987405424 cites W2065269017 @default.
• W1987405424 cites W2065851283 @default.
• W1987405424 cites W2069348560 @default.
• W1987405424 cites W2074369245 @default.
• W1987405424 cites W2074841940 @default.
• W1987405424 cites W2076015650 @default.
• W1987405424 cites W2076812866 @default.
• W1987405424 cites W2081376699 @default.
• W1987405424 cites W2083995804 @default.
• W1987405424 cites W2090051876 @default.
• W1987405424 cites W2090405907 @default.
• W1987405424 cites W2090710882 @default.
• W1987405424 cites W2090856125 @default.
• W1987405424 cites W2095826684 @default.
• W1987405424 cites W2110787316 @default.
• W1987405424 cites W2117486449 @default.
• W1987405424 cites W2126933736 @default.
• W1987405424 cites W2127656637 @default.
• W1987405424 cites W2130746448 @default.
• W1987405424 cites W2136085203 @default.
• W1987405424 cites W2140241341 @default.
• W1987405424 cites W2142368173 @default.
• W1987405424 cites W2149245845 @default.
• W1987405424 cites W2150373693 @default.
• W1987405424 cites W2152069097 @default.
• W1987405424 cites W2155823947 @default.
• W1987405424 cites W2156452034 @default.
• W1987405424 cites W2157194577 @default.
• W1987405424 cites W2168859788 @default.
• W1987405424 cites W2169070800 @default.
• W1987405424 cites W2190055802 @default.
• W1987405424 cites W2219717644 @default.
• W1987405424 cites W2280887441 @default.
• W1987405424 cites W2290574912 @default.
• W1987405424 cites W2313461609 @default.

• next