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- W1987408178 abstract "We have measured the chemical shifts, δ, and ‘second virial shielding coefficient’, σ1, for gaseous 1,1-difluoroethylene and its mixture with other gases at varying pressures (∼ 10–45 atmospheres). The δ vs ρ (density) plot for 1H and 19F resonances is found to be linear within the pressure range studied. The sign of σ1 is negative. The influence of perturbers on δ and σ1 is in the following order: Xe>SF6>Kr>SiF4>CH4>CF4 (spherical top molecules) and C2H6>C2H4>HCl>CO2 (non-spherical top molecules). These trends are true for polar and non-polar solutes." @default.
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- W1987408178 date "1983-04-20" @default.
- W1987408178 modified "2023-09-27" @default.
- W1987408178 title "Pressure dependence of1H and19F chemical shifts in 1,1-difluoroethylene gas and in gaseous mixtures" @default.
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- W1987408178 doi "https://doi.org/10.1080/00268978300100991" @default.
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