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• W1987420512 abstract "Solar furnace melting and fast-quench techniques have been used to prepare SiO2Al2O3 glasses to high alumina content (near 60 mol% Al2O3), which have been studied by Raman spectroscopy. These spectra may not be simply interpreted. The structures of crystalline compounds in the SiO2Al2O3 system are discussed in relation to their vibrational spectra. On the basis of this discussion and other considerations, a structural model for the silica-alumina glass system is proposed, which is consistent with the stable or metastable immiscibility suggested along this join. The essential features of this model include a modified silica structure at low alumina content, and “structure-broken” regions at high alumina compositions, with silicon in tetrahedral coordination, but aluminium assuming a variety of bonding geometries. These are proposed to include aluminate tetrahedra with higher polymerization than simple corner-sharing, and less well-defined polyhedra of higher average coordination number." @default.
• W1987420512 created "2016-06-24" @default.
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• W1987420512 date "1982-12-01" @default.
• W1987420512 modified "2023-10-18" @default.
• W1987420512 title "The structures and vibrational spectra of crystals and glasses in the silica-alumina system" @default.
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• W1987420512 doi "https://doi.org/10.1016/0022-3093(82)90086-2" @default.
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