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• W1987435059 abstract "Why the cysteine dioxygenase (CDO) cannot catalyze the oxidation of selenocysteine (Sec) but that of cysteine (Cys) is still an open question. In order to solve this question, the CDO model complex, the active site of CDO, and their selenium-substituted complexes have been selected as the computational models in this work. The stepwise donation of electron density during the first two reaction steps has been explored. In the first step, the electron density-donor ability of Se to donate to Fe is stronger than that of S; in the second step, S has the better electron density-donor ability to donate to O(2) than Se. Under the influence, in the Cys-bound complexes, the change of the oxidation state for the Fe center is II→III→II, while the Fe center in the Sec-bound complexes remains in the II oxidation state throughout. Considering that the ferric-superoxo species is an active oxidant and exhibits high reactivity in such reaction, it is speculated that the valence change of the Fe center makes the Cys-bound complexes effectively catalyze the oxidation of Cys, while the Sec-bound complexes cannot catalyze the oxidation of Sec. The competition for donation of electron density determines the valence change and the reaction ability." @default.
• W1987435059 created "2016-06-24" @default.
• W1987435059 creator A5018806333 @default.
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• W1987435059 creator A5055616745 @default.
• W1987435059 date "2013-05-01" @default.
• W1987435059 modified "2023-09-26" @default.
• W1987435059 title "Metal vs. chalcogen competition in the catalytic mechanism of cysteine dioxygenase" @default.
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• W1987435059 cites W1967700647 @default.
• W1987435059 cites W1971548560 @default.
• W1987435059 cites W1972000827 @default.
• W1987435059 cites W1975281527 @default.
• W1987435059 cites W1975935952 @default.
• W1987435059 cites W1979169775 @default.
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• W1987435059 doi "https://doi.org/10.1016/j.jinorgbio.2013.01.008" @default.
• W1987435059 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23416309" @default.
• W1987435059 hasPublicationYear "2013" @default.
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