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- W1987441611 abstract "The paramagnetic resonance absorption of Mn ++ ions associated with the impurities of fluorine or divalent anions has been investigated in the single crystals of NaCl and LiCl. A resolved fine structure was observed in a “not quenched crystal” and it did not fade into a broad single line in contrast with the spectra of Mn ++ ions which had been usually observed in alkali halides. The ground level splitting parameters have been determined in the spin Hamiltonian D S 1 2 + E ( S 2 2 - S 3 2 ) as follows: D =(-420±1)·10 -4 cm -1 , | E |=(65±1)·10 -4 cm -1 for Mn ++ –F - , D =(-511±5)·10 -4 cm -1 , | E |=(25±5)·10 -4 cm -1 for Mn ++ –X - , a manganese divalent anion pair, in NaCl, and D =(-672±5)·10 -4 cm -1 , | E |=(12±3)·10 -4 cm -1 for Mn ++ –X - in LiCl, the principal axes of the spin Hamiltonian being in nearly agreement with the cubic axes of the crystal. The large value of D suggests the existence of the strong attractive force between Mn ++ and impurity ion." @default.
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- W1987441611 date "1961-04-01" @default.
- W1987441611 modified "2023-09-23" @default.
- W1987441611 title "Paramagnetic Resonance of Mn<sup>++</sup> Associated with Impurities in Alkali Chlorides" @default.
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- W1987441611 doi "https://doi.org/10.1143/jpsj.16.694" @default.
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