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• W1987444770 abstract "A redox hydrogel with an apparent electron diffusion coefficient (Dapp) of (5.8 ± 0.5) × 10-6 cm2 s-1 is described. The order of magnitude increase in Dapp relative to previously studied redox hydrogels results from the tethering of redox centers to the backbone of the cross-linked redox polymer backbone through 13 atom spacer arms. The long and flexible tethers allow the redox centers to sweep electrons from large-volume elements and to collect electrons of glucose oxidase efficiently. The spacer arms make the collection of electrons from glucose oxidase so efficient that glucose is electrooxidized already at −0.36 V versus Ag/AgCl, the reversible potential of the redox potential of the FAD/FADH2 centers of the enzyme at pH 7.2. The limiting current density of 1.15 mA cm-2 is reached at a potential as low as −0.1 V versus Ag/AgCl. The novel redox center of the polymer is a tris-dialkylated N,N‘-biimidazole Os2+/3+ complex. Its redox potential, −0.195 V versus Ag/AgCl, is 0.8 V reducing relative to that of Os(bpy)2+/3+, its 2,2‘-bipyridine analogue." @default.
• W1987444770 created "2016-06-24" @default.
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• W1987444770 date "2003-03-28" @default.
• W1987444770 modified "2023-10-16" @default.
• W1987444770 title "Long Tethers Binding Redox Centers to Polymer Backbones Enhance Electron Transport in Enzyme “Wiring” Hydrogels" @default.
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• W1987444770 doi "https://doi.org/10.1021/ja029510e" @default.
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