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- W1987445648 abstract "Based on the Hohenberg-Kohn lemma and the hypotheses of the density functional existence for the external-field potential, it is shown that the strict result of the density functional theory is the equation of the external-field potential as the density functional. This result leads to the impossibility of determining the inhomogeneous density in a given external field if the inhomogeneous density is not known a priori. The problem encountered is intimately associated with the absence of a regular procedure for determining the universal density functional. The result obtained shows the advantage of the density matrix functional theory which yields a correct description of the inhomogeneous electron system in both the ideal-gas approximation and the self-consistent Hartree-Fock approximation in contrast to the density functional theory." @default.
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- W1987445648 date "2012-06-01" @default.
- W1987445648 modified "2023-09-26" @default.
- W1987445648 title "External field as the functional of inhomogeneous density and the density matrix functional approach" @default.
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- W1987445648 doi "https://doi.org/10.1209/0295-5075/98/53002" @default.
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