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• W1987447046 abstract "The absorption and fluorescence spectra of Zn porphin in an n-octane single crystal at 4·2 K are reported in the region between 17 400 and 18 500 cm-1. A strong peak appears in both spectra at 17 961 cm-1 and is assigned to the origin of one component (|x, 0>) of the nearly degenerate Q-band. In absorption a second strong line occurs at a frequency δ = 109 cm-1 above the first; a corresponding line is almost totally absent in the emission spectrum at 4·2 K, but it appears as a hot band of appreciable intensity when the temperature is raised to 80 K. This feature is assigned to the origin of the other component (|y, 0>) of the Q-band. The lifting of the degeneracy of the Q-band is interpreted as a crystal field splitting of the Jahn-Teller unstable 1 Eu state. The Zeeman effect is investigated for the 0–0 transition of the phosphorescence spectrum and the |x, 0> and |y, 0> components of the Q-band absorption spectrum. From the phosphorescence experiment it is concluded that the great majority of the ZnP gu..." @default.
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• W1987447046 date "1972-12-01" @default.
• W1987447046 modified "2023-10-14" @default.
• W1987447046 title "Optical and Zeeman studies of the first excited singlet state of zinc porphin in a single crystal ofn-octane: Evidence for Jahn-Teller instability" @default.
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• W1987447046 doi "https://doi.org/10.1080/00268977200102291" @default.
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