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- W1987462040 abstract "Methyl 13-(2-cyclopentenyl)tridecanoate (chaulmoograte) and methyl 13-(2-cyclopentenyl)-cis-6-tridecenoate (gorlate) were hydrogenated using palladium on barium sulfate in hexane. Products obtained by partial hydrogenations were fractionated by argentation thin-layer chromatography, and the components characterised and quantitatively analysed by gas-liquid chromatography, nuclear magnetic resonance spectroscopy, infrared spectroscopy, and reductive ozonolysis. The double bond in position 2 of the cyclopentene ring was found to shift to both positions 1 and 3, but the double bond in position 1 was saturated slower than that either in position 2 or 3. Isomerisation of the ring double bond was faster than its saturation. In methyl gorlate trans-double bonds in the chain accumulated due to their faster formation and slower hydrogenation than cis-double bonds. Saturation of the ring double bond was faster than that of the chain double bond." @default.
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- W1987462040 date "1979-10-01" @default.
- W1987462040 modified "2023-10-14" @default.
- W1987462040 title "Isomerisation and saturation of double bonds in cyclopentenyl fatty acid esters during catalytic hydrogenation" @default.
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- W1987462040 doi "https://doi.org/10.1016/0009-3084(79)90067-7" @default.
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