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- W1987462227 abstract "We reported a new simple route to fabricate N−F-codoped titania inverse opal (IO) films with a hierarchical meso-/macroporous structure, in which the IO structure and the N−F codoping play a role as physical and chemical modifications for titania, respectively. Both modifications are simultaneously achieved via a liquid phase deposition process using a silica colloidal crystal as a template for the first time. The average size of a mesopore in the TiO2 frameworks is 3.2 nm, and that of an interpenetrating aligned macropore is adjusted in the range of 201−315 nm. The N−F-codoped TiO2 IO films exhibit 6.6−7.4 times the methylene blue visible-light photodegradation rate comparing with N−F-codoped TiO2 films without the IO structure. This high visible-light activity was mainly ascribed to a synergetic effect of the hierarchical meso-/macroporous structure and N−F codoping. Furthermore, it was found that the multiple scattering effect of the macroporous structure is more pronounced than the slow photon effect of IOs for facilitating visible-light photocatalysis in our system from the comparison with nonperiodic macroporous N−F-codoped TiO2. The repeated cycling tests revealed that samples showed stable photocatalytic activity." @default.
- W1987462227 created "2016-06-24" @default.
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- W1987462227 date "2010-08-23" @default.
- W1987462227 modified "2023-10-18" @default.
- W1987462227 title "Novel N−F-Codoped TiO<sub>2</sub> Inverse Opal with a Hierarchical Meso-/Macroporous Structure: Synthesis, Characterization, and Photocatalysis" @default.
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- W1987462227 doi "https://doi.org/10.1021/jp101168y" @default.
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