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• W1987463804 startingPage "1278" @default.
• W1987463804 abstract "Halogen atoms Cl, Br, and I steer crystallization of 2-halo-3-hydroxypyridine 1, pyridine-N-oxides 2, and 2-halo-3-aminopyridine 3 in noncentrosymmetric space groups efficient for nonlinear optical materials. Whereas the strong hydrogen-bond chains are aligned antiparallel, the L- or V-geometry of weak interhalogen interaction steers polar alignment in the solid state, even for high dipole moment (μ) halogenated N-oxides 2 (μ > 5.0 D). Six out of seven structures evaluated crystallize in polar/chiral space groups due to interhalogen interactions compared to the one in six probability of noncentrosymmetric packing for achiral molecules." @default.
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• W1987463804 date "2006-05-06" @default.
• W1987463804 modified "2023-10-08" @default.
• W1987463804 title "Using Halogen···Halogen Interactions to Direct Noncentrosymmetric Crystal Packing in Dipolar Organic Molecules" @default.
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• W1987463804 doi "https://doi.org/10.1021/cg060117k" @default.
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