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- W1987473539 abstract "Abstract Three coordination compounds of cobalt(II) acetate with 2-, 3- and 4-aminopyridine were obtained after dissolving Co(CH3COO)2·2H2O and Co(CH3COO)2·4H2O in different solutions of aminopyridines. All three products were characterized magnetically, structurally by single-crystal X-ray diffraction analysis and spectrally by FT-IR spectroscopy. The reaction of Co(CH3COO)2·2H2O with 2-aminopyridine (2-apy) results in the third known modification of a monomeric complex of [Co(O2CCH3)2(2-apy)2] (1) with cis-geometry of the ligands around the metal center. Dark red crystals of the complex, synthesized by the reaction of Co(CH3COO)2·4H2O and 3-aminopyridine (3-apy), result in coordination polymer with the formula {[Co(O2CCH3)2(3-apy)2]·H2O}n (2). Molecular structure of compound 2 consists of a zigzag chain where cobalt(II) ions are connected by 3-aminopyridine ligands. The red crystals, obtained by the reaction of Co(CH3COO)2·4H2O with 4-aminopyridine (4-apy), result in a monomeric complex [Co(O2CCH3)2(4-apy)2(H2O)2] (3) in which the ligands possess trans-geometry around the Co(II) ion. Non-covalent interactions including intra- and intermolecular hydrogen bonds and π–π interactions in the crystal structures of 1–3 is discussed." @default.
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- W1987473539 date "2012-03-01" @default.
- W1987473539 modified "2023-10-18" @default.
- W1987473539 title "Three new cobalt(II) carboxylates with 2-, 3- and 4-aminopyridine: Syntheses, structures and magnetic properties" @default.
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- W1987473539 doi "https://doi.org/10.1016/j.ica.2011.10.056" @default.
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