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- W1987492066 abstract "A condensation reaction of 4-cyanobenzaldehyde (1) with methyl azidoacetate (2) in the presence of sodium methoxide produces a mixture of geometrical isomers of azidocinnamates 3 which undergoes thermolysis to give an indole 4. By contrast, the treatment of 2-cyanobenzaldehyde (5) with 2 in the presence of sodium methoxide and followed by the usual workup furnishes an azepine derivative 6." @default.
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- W1987492066 date "1994-09-01" @default.
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- W1987492066 title "Methoxide ion mediated reactions of methyl azidoacetate with 4-and 2-cyanobenzaldehyde. An unexpected cyclization of the<i>ortho</i>isomer to a 2(1<i>H</i>)-benzazepine derivative" @default.
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- W1987492066 doi "https://doi.org/10.1002/jhet.5570310533" @default.
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