FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1987502918> ?p ?o ?g. }

• W1987502918 abstract "Abstract After detecting vibronic spin–orbit interactions in the triplet-manifold of some anthracene heterocyclics, we were interested in detecting the presence of these interactions in phenanthrene N -heterocyclics. These interactions appear to reduce triplet–triplet (T–T) intensities (oscillator strength f T values) in aromatic heterocyclics. This effect is important to laser dye technology. Reducing T–T absorption intensities in laser dyes results in reduced triplet-state losses and therefore, in higher laser-action efficiencies. To obtain more experimental evidence on this effect, the T–T absorption spectra of phenanthrene, 5,6- and 7,8-benzoquinoline, phenanthridine, and 1,7- and 4,7-phenanthroline over the violet/green spectral region were measured. This is the spectral region where the 3 A 1 − ← 3 B 2 + transition of phenanthrene is located. To obtain these T–T absorption spectra, the steady-state method was employed, using the 337.4 nm line from a cw ion krypton laser for excitation. From the recorded triplet optical densities OD T ( λ ), the triplet extinction coefficients e T ( λ ) were obtained by McClure’s intensity variation method. The triplet oscillator strengths f T of the 3 A 1 − ← 3 B 2 + transition of phenanthrene and the corresponding transitions in the N -heterocyclics were also obtained by integration. Due to measurement errors, the uncertainty of integration limits needed to obtain the f T values, and overlap with neighboring transitions, inconclusive results were obtained for 5,6- and 7,8-benzoquinolines and phenanthridine. However, the f T values for 1,7- and 4,7-phenanthroline were considerably smaller than the f T value obtained for phenanthrene. This suggests the presence of vibronic spin–orbit interactions in these two compounds." @default.
• W1987502918 created "2016-06-24" @default.
• W1987502918 creator A5087432911 @default.
• W1987502918 date "2002-06-01" @default.
• W1987502918 modified "2023-10-03" @default.
• W1987502918 title "Search for vibronic spin–orbit interactions in the triplet-manifold of phenanthrene N-heterocyclic analogues" @default.
• W1987502918 cites W1574706468 @default.
• W1987502918 cites W1970587352 @default.
• W1987502918 cites W1975338132 @default.
• W1987502918 cites W1977662857 @default.
• W1987502918 cites W1987357613 @default.
• W1987502918 cites W1995016599 @default.
• W1987502918 cites W1998234976 @default.
• W1987502918 cites W2002619334 @default.
• W1987502918 cites W2006029797 @default.
• W1987502918 cites W2014492308 @default.
• W1987502918 cites W2018062281 @default.
• W1987502918 cites W2024083646 @default.
• W1987502918 cites W2041489044 @default.
• W1987502918 cites W2045947652 @default.
• W1987502918 cites W2046750600 @default.
• W1987502918 cites W2058044092 @default.
• W1987502918 cites W2067381437 @default.
• W1987502918 cites W2067711500 @default.
• W1987502918 cites W2067913953 @default.
• W1987502918 cites W2087535043 @default.
• W1987502918 cites W2090689944 @default.
• W1987502918 cites W2117918518 @default.
• W1987502918 cites W2621965879 @default.
• W1987502918 cites W342469157 @default.
• W1987502918 cites W560383354 @default.
• W1987502918 cites W654578349 @default.
• W1987502918 doi "https://doi.org/10.1016/s1010-6030(02)00018-7" @default.
• W1987502918 hasPublicationYear "2002" @default.
• W1987502918 type Work @default.
• W1987502918 sameAs 1987502918 @default.
• W1987502918 citedByCount "5" @default.
• W1987502918 countsByYear W19875029182015 @default.
• W1987502918 countsByYear W19875029182017 @default.
• W1987502918 countsByYear W19875029182023 @default.
• W1987502918 crossrefType "journal-article" @default.
• W1987502918 hasAuthorship W1987502918A5087432911 @default.
• W1987502918 hasConcept C113196181 @default.
• W1987502918 hasConcept C119824511 @default.
• W1987502918 hasConcept C120665830 @default.
• W1987502918 hasConcept C121332964 @default.
• W1987502918 hasConcept C1276947 @default.
• W1987502918 hasConcept C178790620 @default.
• W1987502918 hasConcept C185592680 @default.
• W1987502918 hasConcept C2776891815 @default.
• W1987502918 hasConcept C2779563022 @default.
• W1987502918 hasConcept C2780185047 @default.
• W1987502918 hasConcept C32909587 @default.
• W1987502918 hasConcept C4839761 @default.
• W1987502918 hasConcept C71240020 @default.
• W1987502918 hasConcept C75473681 @default.
• W1987502918 hasConcept C76766466 @default.
• W1987502918 hasConcept C99191460 @default.
• W1987502918 hasConceptScore W1987502918C113196181 @default.
• W1987502918 hasConceptScore W1987502918C119824511 @default.
• W1987502918 hasConceptScore W1987502918C120665830 @default.
• W1987502918 hasConceptScore W1987502918C121332964 @default.
• W1987502918 hasConceptScore W1987502918C1276947 @default.
• W1987502918 hasConceptScore W1987502918C178790620 @default.
• W1987502918 hasConceptScore W1987502918C185592680 @default.
• W1987502918 hasConceptScore W1987502918C2776891815 @default.
• W1987502918 hasConceptScore W1987502918C2779563022 @default.
• W1987502918 hasConceptScore W1987502918C2780185047 @default.
• W1987502918 hasConceptScore W1987502918C32909587 @default.
• W1987502918 hasConceptScore W1987502918C4839761 @default.
• W1987502918 hasConceptScore W1987502918C71240020 @default.
• W1987502918 hasConceptScore W1987502918C75473681 @default.
• W1987502918 hasConceptScore W1987502918C76766466 @default.
• W1987502918 hasConceptScore W1987502918C99191460 @default.
• W1987502918 hasLocation W19875029181 @default.
• W1987502918 hasOpenAccess W1987502918 @default.
• W1987502918 hasPrimaryLocation W19875029181 @default.
• W1987502918 hasRelatedWork W1972555505 @default.
• W1987502918 hasRelatedWork W1972924698 @default.
• W1987502918 hasRelatedWork W1977358966 @default.
• W1987502918 hasRelatedWork W1995377756 @default.
• W1987502918 hasRelatedWork W1997789722 @default.
• W1987502918 hasRelatedWork W2000857435 @default.
• W1987502918 hasRelatedWork W2005088595 @default.
• W1987502918 hasRelatedWork W2006029797 @default.
• W1987502918 hasRelatedWork W2019134818 @default.
• W1987502918 hasRelatedWork W2030800801 @default.
• W1987502918 hasRelatedWork W2031965654 @default.
• W1987502918 hasRelatedWork W2044892894 @default.
• W1987502918 hasRelatedWork W2050251262 @default.
• W1987502918 hasRelatedWork W2054151287 @default.
• W1987502918 hasRelatedWork W2076940857 @default.
• W1987502918 hasRelatedWork W2312235177 @default.
• W1987502918 hasRelatedWork W2952926076 @default.
• W1987502918 hasRelatedWork W3041517158 @default.
• W1987502918 hasRelatedWork W2515781980 @default.
• W1987502918 hasRelatedWork W2525207494 @default.
• W1987502918 isParatext "false" @default.
• W1987502918 isRetracted "false" @default.
• W1987502918 magId "1987502918" @default.

• next