FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1987522845> ?p ?o ?g. }

• W1987522845 endingPage "308" @default.
• W1987522845 startingPage "297" @default.
• W1987522845 abstract "Abstract Crystals of (EtO)2P(S)SSSP(S)(OEt)2 are triclinic, P1, with a = 8.388(1), b = 11.128(2), c = 12.518(1) Å, α = 62.34(6), β = 71.93(2), γ = 84.97(5)°, V = 981.6(6) Å3, Z = 2, and D c = 1.36 g/cm3. The final refinement using 3681 observed reflections for 252 variables gives R = 0.057. The two molecules in the elementar cell are conformation enantiomers. The 31P CP MAS spectra show two spinning sideband systems, because the two phosphorus atoms of one molecule are chemically nonequivalent in the crystal. The resolution in the 31C CP MAS spectrum allows to distinguish four lines for the methyl groups and three lines for the methylene groups. NDDO and INDO calculations show, that the conformations with dihedral angles PSSS of ca. 90° have the lowest energies and those with 180 or 0° have considerably higher energies. The relatively high coupling constants 4 J PP of bis-(dialkoxythiophosphoryl)-trisulfanes in solution are not caused by conformations with W-like or other plane positions of the PSSSP nuclei." @default.
• W1987522845 created "2016-06-24" @default.
• W1987522845 creator A5013565453 @default.
• W1987522845 creator A5037641879 @default.
• W1987522845 creator A5053258946 @default.
• W1987522845 creator A5058139309 @default.
• W1987522845 creator A5069619186 @default.
• W1987522845 creator A5080280103 @default.
• W1987522845 date "1993-05-01" @default.
• W1987522845 modified "2023-09-27" @default.
• W1987522845 title "CRYSTAL STRUCTURE, SOLID-STATE NMR, AND QUANTUM CHEMICAL MODEL CALCULATIONS OF BIS-(DIETHOXYTHIOPHOSPHORYL)-TRISULFANE" @default.
• W1987522845 cites W1963546267 @default.
• W1987522845 cites W1966235885 @default.
• W1987522845 cites W1972398864 @default.
• W1987522845 cites W1973899958 @default.
• W1987522845 cites W1976085322 @default.
• W1987522845 cites W1976499505 @default.
• W1987522845 cites W1987205338 @default.
• W1987522845 cites W2010086510 @default.
• W1987522845 cites W2012603801 @default.
• W1987522845 cites W2026324797 @default.
• W1987522845 cites W2034671565 @default.
• W1987522845 cites W2038613322 @default.
• W1987522845 cites W2070070532 @default.
• W1987522845 cites W2081043157 @default.
• W1987522845 cites W2081229357 @default.
• W1987522845 cites W2081688872 @default.
• W1987522845 cites W2083460075 @default.
• W1987522845 cites W2085640145 @default.
• W1987522845 cites W2087138441 @default.
• W1987522845 doi "https://doi.org/10.1080/10426509308032445" @default.
• W1987522845 hasPublicationYear "1993" @default.
• W1987522845 type Work @default.
• W1987522845 sameAs 1987522845 @default.
• W1987522845 citedByCount "5" @default.
• W1987522845 crossrefType "journal-article" @default.
• W1987522845 hasAuthorship W1987522845A5013565453 @default.
• W1987522845 hasAuthorship W1987522845A5037641879 @default.
• W1987522845 hasAuthorship W1987522845A5053258946 @default.
• W1987522845 hasAuthorship W1987522845A5058139309 @default.
• W1987522845 hasAuthorship W1987522845A5069619186 @default.
• W1987522845 hasAuthorship W1987522845A5080280103 @default.
• W1987522845 hasConcept C109214941 @default.
• W1987522845 hasConcept C111429119 @default.
• W1987522845 hasConcept C112887158 @default.
• W1987522845 hasConcept C115624301 @default.
• W1987522845 hasConcept C121332964 @default.
• W1987522845 hasConcept C1276947 @default.
• W1987522845 hasConcept C147597530 @default.
• W1987522845 hasConcept C147789679 @default.
• W1987522845 hasConcept C178790620 @default.
• W1987522845 hasConcept C183276030 @default.
• W1987522845 hasConcept C185592680 @default.
• W1987522845 hasConcept C199360897 @default.
• W1987522845 hasConcept C2781285689 @default.
• W1987522845 hasConcept C32909587 @default.
• W1987522845 hasConcept C41008148 @default.
• W1987522845 hasConcept C42228675 @default.
• W1987522845 hasConcept C4839761 @default.
• W1987522845 hasConcept C486523 @default.
• W1987522845 hasConcept C67787023 @default.
• W1987522845 hasConcept C71240020 @default.
• W1987522845 hasConcept C8010536 @default.
• W1987522845 hasConcept C89025888 @default.
• W1987522845 hasConceptScore W1987522845C109214941 @default.
• W1987522845 hasConceptScore W1987522845C111429119 @default.
• W1987522845 hasConceptScore W1987522845C112887158 @default.
• W1987522845 hasConceptScore W1987522845C115624301 @default.
• W1987522845 hasConceptScore W1987522845C121332964 @default.
• W1987522845 hasConceptScore W1987522845C1276947 @default.
• W1987522845 hasConceptScore W1987522845C147597530 @default.
• W1987522845 hasConceptScore W1987522845C147789679 @default.
• W1987522845 hasConceptScore W1987522845C178790620 @default.
• W1987522845 hasConceptScore W1987522845C183276030 @default.
• W1987522845 hasConceptScore W1987522845C185592680 @default.
• W1987522845 hasConceptScore W1987522845C199360897 @default.
• W1987522845 hasConceptScore W1987522845C2781285689 @default.
• W1987522845 hasConceptScore W1987522845C32909587 @default.
• W1987522845 hasConceptScore W1987522845C41008148 @default.
• W1987522845 hasConceptScore W1987522845C42228675 @default.
• W1987522845 hasConceptScore W1987522845C4839761 @default.
• W1987522845 hasConceptScore W1987522845C486523 @default.
• W1987522845 hasConceptScore W1987522845C67787023 @default.
• W1987522845 hasConceptScore W1987522845C71240020 @default.
• W1987522845 hasConceptScore W1987522845C8010536 @default.
• W1987522845 hasConceptScore W1987522845C89025888 @default.
• W1987522845 hasIssue "1-4" @default.
• W1987522845 hasLocation W19875228451 @default.
• W1987522845 hasOpenAccess W1987522845 @default.
• W1987522845 hasPrimaryLocation W19875228451 @default.
• W1987522845 hasRelatedWork W1551345976 @default.
• W1987522845 hasRelatedWork W2001178185 @default.
• W1987522845 hasRelatedWork W2028390964 @default.
• W1987522845 hasRelatedWork W2030548770 @default.
• W1987522845 hasRelatedWork W2037441916 @default.
• W1987522845 hasRelatedWork W2053154673 @default.
• W1987522845 hasRelatedWork W2094957800 @default.
• W1987522845 hasRelatedWork W2376236816 @default.

• next