FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1987603886> ?p ?o ?g. }

• W1987603886 endingPage "5792" @default.
• W1987603886 startingPage "5783" @default.
• W1987603886 abstract "Magnetic and electric deflection analysis of the scattering of Cs + NO2 shows that the principal product is a paramagnetic, polar molecule. Magnetic analysis of the K + NO2 system indicates that the scattered signal is paramagnetic; a similar study of Na + NO2 shows a small yield of diamagnetic product. For the analogous reactions with CH3NO2, the product is diamagnetic and has a pseudo-first-order Stark effect. From these data and thermochemical arguments the principal alkali-containing products are identified as: for Cs + NO2, a 2Σ electronic state of CsO; for Na + NO2, probably a 2Π state of NaO; for M + CH3NO2, almost certainly MNO2 in a singlet state. The NO2 results indicate that the ground state of the MO molecule changes from 2Π for LiO (the only species which had been previously observed) to 2Σ for CsO. The usual differential surface ionization detection fails for Cs + NO2 and consequently only a very rough estimate of the scattering is obtained; this indicates that the total reaction cross section is ∼ 100 Å2. For the CH3NO2 reactions differential surface ionization is applicable. Again the reaction cross sections are ∼ 100 Å2 and increase as Na→K→Cs. The c.m. product angular distribution is broad, with about the same intensity in the forward and backward hemispheres. These results are discussed in terms of the electronic structure of the reactant and product molecules and contrasted with reactions of alkali atoms with halogen-containing molecules. Scattering of related molecules has also been studied briefly, including RONO and R′ONO2 (with R = i-C5H11 and R′ = C2H5), which give diamagnetic products with yields very similar to CH3NO2, and N2O and R″OOR″ (with R″ = t-C4H9), for which only paramagnetic species were observed." @default.
• W1987603886 created "2016-06-24" @default.
• W1987603886 creator A5000346379 @default.
• W1987603886 creator A5014061181 @default.
• W1987603886 date "1970-06-01" @default.
• W1987603886 modified "2023-10-09" @default.
• W1987603886 title "Molecular Beam Kinetics: Reactions of Alkali Atoms with NO2 and CH3NO2" @default.
• W1987603886 cites W139266827 @default.
• W1987603886 cites W1552223585 @default.
• W1987603886 cites W1967329131 @default.
• W1987603886 cites W1974707754 @default.
• W1987603886 cites W1978256245 @default.
• W1987603886 cites W1978988987 @default.
• W1987603886 cites W1991339701 @default.
• W1987603886 cites W1996161904 @default.
• W1987603886 cites W2013531327 @default.
• W1987603886 cites W2014187095 @default.
• W1987603886 cites W2024647058 @default.
• W1987603886 cites W2028023613 @default.
• W1987603886 cites W2037391101 @default.
• W1987603886 cites W2037499947 @default.
• W1987603886 cites W2037504975 @default.
• W1987603886 cites W2038527810 @default.
• W1987603886 cites W2040120187 @default.
• W1987603886 cites W2041008107 @default.
• W1987603886 cites W2041126752 @default.
• W1987603886 cites W2045503661 @default.
• W1987603886 cites W2049168747 @default.
• W1987603886 cites W2054963433 @default.
• W1987603886 cites W2056950688 @default.
• W1987603886 cites W2057671083 @default.
• W1987603886 cites W2061831865 @default.
• W1987603886 cites W2064344915 @default.
• W1987603886 cites W2064773361 @default.
• W1987603886 cites W2072181490 @default.
• W1987603886 cites W2078264594 @default.
• W1987603886 cites W2080005643 @default.
• W1987603886 cites W2082169361 @default.
• W1987603886 cites W2088227313 @default.
• W1987603886 cites W2090436206 @default.
• W1987603886 cites W2110490954 @default.
• W1987603886 cites W2117907308 @default.
• W1987603886 cites W2135237683 @default.
• W1987603886 cites W2149735841 @default.
• W1987603886 cites W2162665190 @default.
• W1987603886 cites W2163863241 @default.
• W1987603886 cites W2320704623 @default.
• W1987603886 cites W2322019726 @default.
• W1987603886 cites W66499140 @default.
• W1987603886 doi "https://doi.org/10.1063/1.1672860" @default.
• W1987603886 hasPublicationYear "1970" @default.
• W1987603886 type Work @default.
• W1987603886 sameAs 1987603886 @default.
• W1987603886 citedByCount "100" @default.
• W1987603886 countsByYear W19876038862015 @default.
• W1987603886 countsByYear W19876038862017 @default.
• W1987603886 countsByYear W19876038862018 @default.
• W1987603886 countsByYear W19876038862019 @default.
• W1987603886 countsByYear W19876038862020 @default.
• W1987603886 countsByYear W19876038862021 @default.
• W1987603886 countsByYear W19876038862022 @default.
• W1987603886 crossrefType "journal-article" @default.
• W1987603886 hasAuthorship W1987603886A5000346379 @default.
• W1987603886 hasAuthorship W1987603886A5014061181 @default.
• W1987603886 hasConcept C113196181 @default.
• W1987603886 hasConcept C115260700 @default.
• W1987603886 hasConcept C120665830 @default.
• W1987603886 hasConcept C121332964 @default.
• W1987603886 hasConcept C124712363 @default.
• W1987603886 hasConcept C145148216 @default.
• W1987603886 hasConcept C178790620 @default.
• W1987603886 hasConcept C181500209 @default.
• W1987603886 hasConcept C184779094 @default.
• W1987603886 hasConcept C185592680 @default.
• W1987603886 hasConcept C191486275 @default.
• W1987603886 hasConcept C198091228 @default.
• W1987603886 hasConcept C198291218 @default.
• W1987603886 hasConcept C2777734200 @default.
• W1987603886 hasConcept C2780263894 @default.
• W1987603886 hasConcept C32909587 @default.
• W1987603886 hasConcept C33062035 @default.
• W1987603886 hasConcept C46062151 @default.
• W1987603886 hasConcept C54419926 @default.
• W1987603886 hasConcept C62520636 @default.
• W1987603886 hasConcept C96026104 @default.
• W1987603886 hasConceptScore W1987603886C113196181 @default.
• W1987603886 hasConceptScore W1987603886C115260700 @default.
• W1987603886 hasConceptScore W1987603886C120665830 @default.
• W1987603886 hasConceptScore W1987603886C121332964 @default.
• W1987603886 hasConceptScore W1987603886C124712363 @default.
• W1987603886 hasConceptScore W1987603886C145148216 @default.
• W1987603886 hasConceptScore W1987603886C178790620 @default.
• W1987603886 hasConceptScore W1987603886C181500209 @default.
• W1987603886 hasConceptScore W1987603886C184779094 @default.
• W1987603886 hasConceptScore W1987603886C185592680 @default.
• W1987603886 hasConceptScore W1987603886C191486275 @default.
• W1987603886 hasConceptScore W1987603886C198091228 @default.
• W1987603886 hasConceptScore W1987603886C198291218 @default.

• next