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• W1987633021 abstract "Water droplets were formed spontaneously at the interface of the 2-nitrophenyloctyl ether and aqueous phases on the oil phase side when the oil contained tetraalkylammonium chloride without surfactants. The droplets, less than some micrometers in diameter, gathered at the interface. The number density of the droplets was proportional to the concentration of tetraethylammonium chloride, and hence this salt should be responsible for the formation of the droplets as a surfactant. When positive voltage was applied to the aqueous phase against the oil, the droplets departed from the interface toward the oil bulk. The droplets should be negatively charged by chloride. The adsorption model of the salt was suggested, in which chloride is immobilized at the interface on the aqueous side electrostatically with tetraethylammonium ion on the oil side." @default.
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• W1987633021 date "2009-02-01" @default.
• W1987633021 modified "2023-09-27" @default.
• W1987633021 title "Spontaneous emulsification at oil–water interface by tetraalkylammonium chloride" @default.
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• W1987633021 doi "https://doi.org/10.1016/j.elecom.2008.11.012" @default.
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