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• W1987650820 endingPage "53" @default.
• W1987650820 startingPage "47" @default.
• W1987650820 abstract "The chloride ligand in the diastereomer mixture (RRu,SC)- and (SRu,SC)-[(η6-C6H6)Ru(LL∗)Cl], 1a and 1b (ratio 86:14), was abstracted in acetone at −30 to −40°C by AgPF6 [HLL∗ = (S)-(1-phenylethyl)salicylaldimine]. X-ray analysis of crystals of the product [(η6-C6H6)Ru(LL∗)]2(PF6)2 · 2CO(CH3)23 shows a dimeric structure with opposite ruthenium configurations. Therefore, the dimer containing two salicylaldiminato ligands with the same chirality can be described as a “quasi-meso” stereoisomer. The complex is supposed to be formed from the solvate complexes with coordinated acetone during crystallisation. This assumption is in accord with the reactivity of 3 towards water in acetone. A conformational analysis based on the NMR spectroscopic results shows that the arrangement of the 1-phenylethyl groups relative to the [(η6-C6H6)Ru(LL∗)] fragments is determined by the face-on orientation of the phenyl substituent with respect to the π-bonded benzene ligands." @default.
• W1987650820 created "2016-06-24" @default.
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• W1987650820 date "1996-07-01" @default.
• W1987650820 modified "2023-09-23" @default.
• W1987650820 title "Optically active transition metal complexes. Part 108. Synthesis, crystal structure and properties of a novel “quasi-meso” dinuclear η6-benzene-ruthenium(II) complex with chiral salicylaldiminato ligands" @default.
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• W1987650820 doi "https://doi.org/10.1016/0022-328x(96)06210-9" @default.
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