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- W1987663196 abstract "Flow-through microreactors are described, constructed of fused silica capillaries with an internal diameter of 100 μm and glass microchips with a channel dimension of 150 μm and involving the in situ UV-initiated synthesis of a poly(glycidyl methacrylate-co-ethylene dimethacrylate) porous polymer monolith. The monolith is a continuous material covalently bonded to the capillary or chip walls, with good flow-through properties. Epoxide ring-opening through amine attack by 5-amino-1,10-phenanthroline and coordination to dichloropalladium(ii) allows use of the microreactors for Suzuki–Miyaura catalysis. The long-term stability and reliability of the robust chip microreactor is demonstrated by operation for 96 h, exhibiting undiminished reactivity, and very low leaching of palladium." @default.
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- W1987663196 date "2008-01-01" @default.
- W1987663196 modified "2023-09-23" @default.
- W1987663196 title "Microfluidic Devices for Flow-Through Supported Palladium Catalysis on Porous Organic Monolith" @default.
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- W1987663196 doi "https://doi.org/10.1071/ch08160" @default.
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