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• W1987687572 abstract "Abstract Two novel dicyanamide complexes [Co(dmf) 2 (NCNCN) 2 ] ( 1 ) and [Cu(bipy)(NCNCN)]ClO 4 ( 2 ) have been synthesized and structurally characterized. 1 crystallizes in the monoclinic space group C 2 with a = 13.568(6)Å, b = 7.403(3)Å, c = 8.118(3)Å and Z = 2, whereas 2 crystallizes in the monoclinic system, Cc group, a = 14.270(7)Å, b = 9.143(5)Å, c = 12.371(1) Å, β = 118.612(7)°, and Z = 4. According to X‐ray crystallographic studies, in complex 1 each Co II ion is six‐coordinated with four nitrogen atoms from four μ 1, 5 ‐dca (dca = dicyanamide) ligands and two oxygen atoms from two dmf ligands to form distorted octahedra. 1 forms a 1‐D network bridged via μ 1, 5 ‐dca. 2 consists of a uniform Cu(NCNCN)Cu chain, each Cu II ion is octahedrally coordinated with four nitrogen atoms from two μ 1, 5 ‐dca ligands and one bipy ligand and two oxygen atoms from two ClO 4 — ions. The octahedral Cu II ion shows a significant Jahn‐Teller distortion, with two axial oxygen atoms considerably farther from the copper than the four equatorial nitrogens." @default.
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• W1987687572 date "2003-12-01" @default.
• W1987687572 modified "2023-10-18" @default.
• W1987687572 title "Syntheses and Structures of two 1-D Complexes, [Co(dmf)2(NCNCN)2] and [Cu(bipy)(NCNCN)]ClO4 with Bridging Dicyanamide Ligands" @default.
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• W1987687572 doi "https://doi.org/10.1002/zaac.200300284" @default.
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