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- W1987692704 abstract "The 1-C-nitroglycosyl chloride reacted with the anions form 2-nitropropane, nitromethane, and diethyl malonate, to give the chain-extended products 2 (81%), 5 (72%), and 6 (83%), respectively. Treatment of the 1-C -nitroglycosyl bromide 7 by the lithium salt obtained form 8 gave the dodecodiulose derivative 9 (76%). Th β-D-configuration of 2 and 9 was inferred form their NMR and CD spectra. Treatment of 2 and 9 with sodium sulfide gave the enol ethers 3 (96%) and 10 (92%), respectively. The (Z)-configuration of 10 was deduced form the configuration of its hydrogenation product 11." @default.
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- W1987692704 date "1984-12-19" @default.
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- W1987692704 title "Deoxy-nitrosugars. 9th communication. Chain elongation of 1-C -nitroglycosyl halides by substitution with some weakly basic carbanions" @default.
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- W1987692704 doi "https://doi.org/10.1002/hlca.19840670828" @default.
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