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- W1987702010 abstract "Sub-micrometric β-CoMoO4 rods have been obtained after thermal treatment of CoMoO4·H2O previously prepared by the precipitation method. The color of the sub-micrometric particles has been investigated through diffuse reflectance in the VIS-IR range and the spectra have been compared with those corresponding to samples with larger isotropic particles. The O2−→Mo6+ charge transfer band shifts to the UV region with decreasing the particle size, revealing a more covalent bond. This can be justified under the consideration of a higher proportion of surface-atoms in sub-micrometric particles that present lower coordination number. The piezochromic behavior of the sub-micrometric β-CoMoO4 rods has been investigated. As the sub-micrometric size of the particles stabilizes the low-coordination phase (β-phase), the transition pressure to the α-phase is higher in comparison with that corresponding to larger particles. In addition, it was not possible to obtain a 100% transformation of the β-phase in the sample with sub-micrometric particles. A similar temperature influence on the transition pressure regardless of particle size has also been observed." @default.
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- W1987702010 date "2013-01-01" @default.
- W1987702010 modified "2023-10-01" @default.
- W1987702010 title "Sub-micrometric β-CoMoO4 rods: optical and piezochromic properties" @default.
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- W1987702010 doi "https://doi.org/10.1039/c3dt51656c" @default.
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