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• W1987743323 abstract "Abstract We report new measurements of the spectra of argon in the discrete and autoionizing region using two-step laser excitation and optogalvanic detection technique. By selecting a particular intermediate level, we have been able to isolate a Rydberg series of specific K and J values. The 3p 5 n d[ 3 2 ] 2 , 3p 5 n d[ 5 2 ] 2 and 3p 5 n d[ 5 2 ] 3 Rydberg series, converging to both 3p 5 ( 2 P 3 2 ) and 3p 5 ( 2 P 1 2 ) limits have been excited from the 3p 5 4p[ 1 2 ] 1 , 3p 5 4p[ 3 2 ] 1 and 3p 5 4p[ 3 2 ] 2 intermediate levels which are being populated from the 3p 5 4s[ 3 2 ] 2 metastable level. The three perturbers 3p 5 ( 2 P 1 2 )8d′[ 3 2 ] 2 , 3p 5 ( 2 P 1 2 )8d′[ 5 2 ] 2 and 3p 5 ( 2 P 1 2 )8d′[ 5 2 ] 3 are clearly identified and their interactions with the respective series have been studied using multichannel quantum defect theory. The parameters obtained by fitting the lines shapes of the corresponding autoionizing resonances adjacent to the first ionization threshold 3p 5 ( 2 P 1 2 )9d′[ 3 2 ] 2 , 3p 5 ( 2 P 1 2 )9d′[ 5 2 ] 2 and 3p 5 ( 2 P 1 2 )9d′[ 5 2 ] 3 show good correlation with those determined from the series perturbation analysis in the discrete region. It is remarked that only a two channel quantum defect model is sufficient to describe the series perturbations and the autoionization phenomena." @default.
• W1987743323 created "2016-06-24" @default.
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• W1987743323 date "1999-12-01" @default.
• W1987743323 modified "2023-10-17" @default.
• W1987743323 title "Observation of 3p5nd J = 2, 3 odd parity spectra of argon and MQDT analysis in the discrete and autoionizing regions" @default.
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• W1987743323 doi "https://doi.org/10.1016/s0030-4018(99)00525-8" @default.
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