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- W1987753380 abstract "Two coordination polymers (CPs) based on a AgI/perfluoro-β-diketonate/N-donor ligand, [Ag(4,4′-bpy)(hfa)]n, (1) and [Ag(4,4′-bpy)(ttfa)]n (2), where 4,4′-bpy is 4,4′-bipyridine, Hhfa is hexafluoroacetylacetone, and Httfa is thenoyltrifluoracetylacetone, were prepared and characterized by elemental analysis, IR and 1H NMR spectroscopy as well as X-ray crystallography and electrochemical properties were studied. The complexes display 1D CPs structurally quite similar to another. The adjacent chains are further interlinked via Ag···Ag, Ag···O contacts to generate 1D ladder (double chains) structures. Abundant weak interactions, such as π···π, CH···F, CH···O and F···F interactions, provide additional assembly forces, leading to 3D supramolecular networks for 1 and 2." @default.
- W1987753380 created "2016-06-24" @default.
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- W1987753380 date "2011-12-01" @default.
- W1987753380 modified "2023-09-30" @default.
- W1987753380 title "Two new silver(I) coordination polymers with 4,4′-bipyridine and two perfluoro-β-diketonates" @default.
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- W1987753380 doi "https://doi.org/10.1016/j.molstruc.2011.08.059" @default.
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