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• W1987756013 endingPage "1002" @default.
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• W1987756013 abstract "Studies of hydrogen isothermal desorption and abstraction from polycrystalline diamond surfaces are presented. The surface H and D coverages (θH and θD) are measured in real time by mass analyzing the recoiled ions generated in a time-of-flight scattering and recoil spectroscopy (TOF-SARS) experiment. For surface temperatures (Ts) from 825 and 920 °C, isothermal H2 desorption is 1st order in θH with a measured activation energy, ET, of 69±6 kcal/mol and a pre-exponential factor, ν, of 1010.5±0.9 s−1. For H2 desorption from diamond, the estimated ΔET based on bond energy calculations is ≊88 kcal/mol, substantially higher than the experimentally measured ET. This difference suggests π-bonding of the surface after H2 desorption is involved. Using a simple bond order argument, the π-bonding contribution is estimated to be ≊21 kcal/mol. The abstraction and replacement of absorbed H by atomic deuterium (Dat) is explained by three first-order reactions. Under a constant Dat flux, the rate of abstraction of adsorbed H by Dat is 1st order in θH, with an ‘‘apparent activation energy’’ (Ea) of 0.8±0.2 kcal/mol and ν=(1.3±0.2)10−3 s−1. The low Ea and 1st order kinetics imply that H is abstracted from the surface by a generalized Eley–Rideal or direct mechanism. Using the relative rate of Dat abstraction of H to Dat adsorption on clean diamond, we estimate an upper limit for the abstraction activation barrier of 16 kcal/mol. Under identical reaction conditions, the rate for Hat abstraction of D is ≊1/3 the rate for Dat abstraction of H. We interpret this isotope effect using momentum transfer arguments." @default.
• W1987756013 created "2016-06-24" @default.
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• W1987756013 date "1995-01-08" @default.
• W1987756013 modified "2023-09-28" @default.
• W1987756013 title "Hydrogen on polycrystalline diamond films: Studies of isothermal desorption and atomic deuterium abstraction" @default.
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• W1987756013 doi "https://doi.org/10.1063/1.469167" @default.
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