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- W1987777855 abstract "The photodissociation dynamics of carbon dioxide cation, ${rm CO}_{rm 2}^ +$ CO 2+, mediated by its different $tilde A{}^{rm 2}Pi _{u,1/2} (upsilon _1,upsilon _2,0)$ÃΠu,1/22(υ1,υ2,0) vibronic states has been investigated by means of time-sliced velocity map imaging. Through analysis of the recorded translational energy release spectra of photofragment CO+, we found that the photodissociation of ${rm CO}_{rm 2}^ +$ CO 2+ exhibits drastic change in a rather narrow energy region. A conformational barrier in the ${rm CO}_{rm 2}^ + ( {tilde A{}^{rm 2}A_1 } )$ CO 2+(ÃA12) state is suggested to be ∼5600 cm−1 relative to the ${rm CO}_{rm 2}^ + ( {tilde A{}^{rm 2}Pi _{u,1/2} ( {0,0,0} )})$ CO 2+(ÃΠu,1/22(0,0,0)) state, in reasonable agreement with previous prediction." @default.
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- W1987777855 date "2013-10-25" @default.
- W1987777855 modified "2023-10-16" @default.
- W1987777855 title "Note: Vibrationally mediated photodissociation of carbon dioxide cation" @default.
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- W1987777855 doi "https://doi.org/10.1063/1.4827105" @default.
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