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- W1987808218 endingPage "3152" @default.
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- W1987808218 abstract "Complexes formed by interaction of excess 2,6-lutidine N-oxide (LNO) with various metal nitrates and thiocyanates were prepared and characterized by means of spectral, magnetic and conductance studies, as follows: [M(LNO)6](NO3)3 (M = Cr, Fe), involving distorted octahedral complex cations and ionic nitrate; [M(LNO)2(ONO2)(O2NO)] (MMn, Co, Ni, Zn), pentaco-ordinated neutral complexes, containing one mono- and one bi-dentate nitrato groups; [Cu(LNO)2(ONO2)2], planar, and [Cd(LNO)4(ONO2)2], hexaco-ordinated, with monodentate nitrato ligands; [(LNO)(SCN)2−Mg(LNO)2Mg(NCS)2(LNO)], dimeric, pentaco-ordinated, LNO-bridged, with N-bonded thiocyanate; [(NCS)2Hg(LNO)2Hg(SCN)2], dimeric, tetrahedral, LNO-bridged, with S-bonded thiocyanate; [(LNO)2(SCN)M(NCS)2M(NCS)(LNO)2] (M Co, Ni), pentaco-ordinated dimers with terminal isothiocyanato as well as bridging NCS groups; and [Cu(LNO)2(NCS)2]x, hexaco-ordinated polymeric complex with bridging NCS ligands. [Fe(LNO)6](NO3)3 is the first example of a compound characterized by the FeIIIO6 moiety and exhibiting spin-free-spin-paired equilibria; the polymeric [Cu(LNO)2(NCS)2]x exhibits a subnormal magnetic moment. The influence of the steric effects of LNO on the types of complexes formed is discussed." @default.
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- W1987808218 date "1972-10-01" @default.
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- W1987808218 title "Metal nitrate and thiocyanate complexes with 2,6-lutidine n-oxide" @default.
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- W1987808218 doi "https://doi.org/10.1016/0022-1902(72)80111-8" @default.
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