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• W1987874607 abstract "A technique has been developed that provides a solution to the very considerable technical problem of preparing gas-phase complexes from transition metals in their higher oxidation states, i.e., Cu(II), Cr(III), Fe(II), etc. Charge transfer prevents complexes, such as [Cu·(H2O)n]2+, from being prepared via nucleation about an ion core, and yet these ions are pivotal to an understanding of transition metal chemistry. Discussed here are new results from a technique that appears capable of producing complexes from a wide variety of metals and ligands. Data are presented for copper(II) in association with 20 different ligands, including water, ammonia, pyridine, tetrahydrofuran, and benzene. For each [Cu·Ln]2+ system, two important quantities are identified: (i) the minimum number of ligands required to form a stable unit and (ii) the value of n for which the intensity distribution reaches a maximum. The data show considerable variation as a function of the composition and size of solvent molecule, with evidence of stable coordination shells containing between 2 and 8 molecules. In most instances, coordination shells containing more than four molecules can be attributed to the formation of an extended network of hydrogen bonds. Collisional activation of size-selected clusters reveals the presence of extensive ligand-to-metal electron transfer in the smaller complexes, and in several cases, charge transfer is also accompanied by chemical reactivity. The extent of charge transfer is frequently observed to be determined by the stability of the singly charged metal-containing product." @default.
• W1987874607 created "2016-06-24" @default.
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• W1987874607 date "2000-12-15" @default.
• W1987874607 modified "2023-10-16" @default.
• W1987874607 title "Coordination and Chemistry of Stable Cu(II) Complexes in the Gas Phase" @default.
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• W1987874607 doi "https://doi.org/10.1021/jp002682i" @default.
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