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- W1987915246 abstract "Abstract On the Stabilization of Suboxide Phases by Carbide Ions: The Crystal Structure of Sr 21 Si 2 O 5 C 6 Metallic brass‐coloured crystals of Sr 21 Si 2 O 5 C 6 were isolated from samples starting from the educts Sr : SiO : C = 21 : 2 : 6 heated under argon atmosphere in corundum crucibles up to 1150 K. The air‐sensitive compound crystallizes in the cubic system, space group $F d : overline{mathit{3}} : m, a$ = 1914,56(19) pm, Z = 8. In the crystal structure the Si, O and C atoms are coordinated only by Sr atoms forming distorted icosahedra around Si and distorted octahedra around O and C. The compound can be classified as an electron precise Zintl phase according to (Sr 2+ ) 21 (Si 4− ) 2 (O 2− ) 5 (C 4− ) 6 ." @default.
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- W1987915246 date "2005-04-18" @default.
- W1987915246 modified "2023-10-16" @default.
- W1987915246 title "Zur Stabilisierung von Suboxidphasen durch Carbidionen: Die Kristallstruktur von Sr21Si2O5C6" @default.
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- W1987915246 doi "https://doi.org/10.1002/zaac.200500023" @default.
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