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• W1987943437 abstract "The effect of MII substitution on the magnitude of the negative thermal expansion (NTE) behavior within a series of Prussian Blue analogues, MIIPtIV(CN)6 for MII = Mn, Fe, Co, Ni, Cu, Zn, Cd, has been investigated using variable-temperature powder X-ray diffraction (100−400 K). The NTE behavior varies widely with MII substitution, from near zero thermal expansion in NiPt(CN)6 (α = dl/l dT = −1.02(11) × 10-6 K-1) up to a maximum in CdPt(CN)6 (α = −10.02(11) × 10-6 K-1). The trend in the magnitude of the NTE behavior, with increasing atomic number (Z) of the MII ion, follows the order MnII > FeII > CoII > NiII < CuII < ZnII < CdII, which correlates with the trends for MII cation size, the lattice parameter, and structural flexibility as indicated by the temperature-dependent structural refinements and Raman spectroscopy. Analysis of the temperature dependence of the average structures suggests that the differences in the thermal expansion are due principally to the different strengths of the metal−cyanide binding interaction and, accordingly, the different energies of transverse vibration of the cyanide bridge, with enhanced NTE behavior for more flexible lattices." @default.
• W1987943437 created "2016-06-24" @default.
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• W1987943437 date "2006-05-01" @default.
• W1987943437 modified "2023-10-02" @default.
• W1987943437 title "Compositional Dependence of Negative Thermal Expansion in the Prussian Blue Analogues M^IIPt^IV(CN)₆ (M = Mn, Fe, Co, Ni, Cu, Zn, Cd)" @default.
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• W1987943437 doi "https://doi.org/10.1021/ja060916r" @default.
• W1987943437 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16719481" @default.
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