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- W1987980991 abstract "A series of amine radical cations with α-silyl substitutents has been studied by EPR spectroscopy, following γ-radiolysis of dilute solutions of the parent amines in CFCl3 at 77 K. It is clear that the nitrogen centred singly occupied molecular orbitals (SOMOs) are delocalised and extend appreciably onto the silyl groups, as shown by a fall in the magnitude of the anisotropic 14N couplings from those found in alkylamine radical cations, and thus the concept of Si–N dπ–pπ bonding in silylamines is strongly supported. The results contrast with prior conclusions for the isoelectronic alkyl radicals i.e. the extent of spin delocalisation onto the silyl group is negligible." @default.
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- W1987980991 date "1992-01-01" @default.
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- W1987980991 title "Direct EPR evidence for Si–N dπ–pπ bonding in silylamine radical cations" @default.
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- W1987980991 doi "https://doi.org/10.1039/p29920000235" @default.
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