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- W1987985475 abstract "Abstract Crystallization rates, from the melts of linear polyethylene and ethylene—butadiene copolymers, have been measured by differential thermal analysis. The effect of the intra-chain double bonds on the crystallization is discussed. The results are analysed in terms of the Avrami equation. Analysis of the dependence of the rate of crystallization on the undercooling shows that the growth of the spherulites is controlled by a process of surface secondary coherent nucleation. The free energy of formation of a nucleus of critical dimensions depend upon the number of trans double bonds in the polymer chain." @default.
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- W1987985475 date "1975-12-01" @default.
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- W1987985475 title "Effect of intra-chain double bonds on the crystallization of polyethylene from the melt" @default.
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- W1987985475 doi "https://doi.org/10.1016/0032-3861(75)90204-9" @default.
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