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- W1987992073 abstract "The synthesis and characterization of two new silicon-carbon bridged ansa -bis(fluorenyl) and ansa -bis(octahydrofluorenyl) zirconocene complexes, (Flu−CH 2 −SiMe 2 −Flu)ZrCl 2 ( 3 ) and (FluH 8 −CH 2 −SiMe 2 −FluH 8 )ZrCl 2 ( 4 ) is reported. Complex 3 , in combination with methylaluminoxane (MAO), forms an active catalyst system for homogeneous polymerization of ethylene. The molecular structure of 4 reveals a large Centroid-Zr-Centroid angle (131.9°) and an unusually small Cl−Zr−Cl angle (93.2°). The Zr−C bond distances range from 2.48 to 2.64 A." @default.
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- W1987992073 date "1997-01-01" @default.
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- W1987992073 title "Silicon-carbon bridged bis(fluorenyl) and bis(octahydrofluorenyl) ansa-zirconocenes: synthesis, characterization and ethylene polymerization catalysis" @default.
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- W1987992073 doi "https://doi.org/10.1016/s0022-328x(97)00250-7" @default.
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