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- W1987995142 abstract "[Sr2Cu(C2O4)3(H2O)7](C2O42–= oxalate ion) has been synthesized and characterized. The structure has been determined by X-ray diffraction methods. It crystallizes in the triclinic system, space group Pī with a= 6.349(2)A, b= 10.258(2)A, c= 15.737(2)A, α= 73.21(1)°, β= 93.66(2)°, γ= 76.44(2)°, V= 944.3(4)A3, Z= 2. The structure consists of an intricate network of Sr2+ and Cu2+ ions linked by oxalate and H2O groups. A nonacoordinated arrangement around the two strontium ions and a distorted octahedral geometry for the copper(II) ions are observed. The thermal decomposition of this complex yields a unique and homogeneous phase at comparatively short reaction times and lower temperatures than the ceramic method. Conductivity measurements of the oxide obtained show semiconductor behaviour." @default.
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- W1987995142 date "1994-01-01" @default.
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- W1987995142 title "Synthesis, crystal structure and properties of [Sr2Cu(C2O4)3(H2O)7]: precursor of Sr2CuO3oxide" @default.
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- W1987995142 doi "https://doi.org/10.1039/jm9940401867" @default.
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