Matches in SemOpenAlex for { <https://semopenalex.org/work/W1987998315> ?p ?o ?g. }
Showing items 1 to 62 of
62
with 100 items per page.
- W1987998315 endingPage "367" @default.
- W1987998315 startingPage "359" @default.
- W1987998315 abstract "The reduction of hydrogen peroxide at the D.M.E. is catalyzed in lanthanum, salt solutions. In. 0.01 M La(NO3)3 it has been shown that a cathodic hydrogen peroxide current appears at +0.2 V vs. S.C.E., followed by a depression in the current which extends to the main hydrogen peroxide wave at −0.3 V. Experiments on suspensions of lanthanum hydroxide in lanthanum nitrate-hydrogen peroxide solutions have shown that the reduction current at potentials more oxidizing than −0.3 V increased upon contact with the solid, while the height of the normal wave decreased. Filtration of these mixtures and tests with potassium permanganate and nitric acid on the filtrate indicated that the species responsible for the reduction current was soluble, oxidizable, and unstable to acid. Mercury in contact with the lanthanum nitratehydrogen peroxide test solution led to the more rapid production of this species along with the evolution of oxygen. A soluble complex between lanthanum ion and hydrogen peroxide, formed under mildly alkaline conditions, is postulated as the species being reduced. The suppression of the catalytic current in the potential range +0.1 to −0–2 V is interpreted as the result of adsorption of insoluble lanthanum hydroxide or polymeric lanthanum hydroxy-complexes on the D.M.E. Current-time curves consistent with this explanation have been obtained." @default.
- W1987998315 created "2016-06-24" @default.
- W1987998315 creator A5069081317 @default.
- W1987998315 creator A5089561688 @default.
- W1987998315 date "1964-05-01" @default.
- W1987998315 modified "2023-09-27" @default.
- W1987998315 title "Polarography of hydrogen peroxide in lanthanum nitrate solutions" @default.
- W1987998315 cites W2094685761 @default.
- W1987998315 cites W2312314898 @default.
- W1987998315 cites W2327706308 @default.
- W1987998315 cites W2330599379 @default.
- W1987998315 doi "https://doi.org/10.1016/0022-0728(64)80024-3" @default.
- W1987998315 hasPublicationYear "1964" @default.
- W1987998315 type Work @default.
- W1987998315 sameAs 1987998315 @default.
- W1987998315 citedByCount "1" @default.
- W1987998315 crossrefType "journal-article" @default.
- W1987998315 hasAuthorship W1987998315A5069081317 @default.
- W1987998315 hasAuthorship W1987998315A5089561688 @default.
- W1987998315 hasConcept C161790260 @default.
- W1987998315 hasConcept C178790620 @default.
- W1987998315 hasConcept C179104552 @default.
- W1987998315 hasConcept C185592680 @default.
- W1987998315 hasConcept C2775885272 @default.
- W1987998315 hasConcept C2775896084 @default.
- W1987998315 hasConcept C2778504605 @default.
- W1987998315 hasConcept C2781048764 @default.
- W1987998315 hasConcept C533411734 @default.
- W1987998315 hasConcept C555894677 @default.
- W1987998315 hasConcept C77176794 @default.
- W1987998315 hasConceptScore W1987998315C161790260 @default.
- W1987998315 hasConceptScore W1987998315C178790620 @default.
- W1987998315 hasConceptScore W1987998315C179104552 @default.
- W1987998315 hasConceptScore W1987998315C185592680 @default.
- W1987998315 hasConceptScore W1987998315C2775885272 @default.
- W1987998315 hasConceptScore W1987998315C2775896084 @default.
- W1987998315 hasConceptScore W1987998315C2778504605 @default.
- W1987998315 hasConceptScore W1987998315C2781048764 @default.
- W1987998315 hasConceptScore W1987998315C533411734 @default.
- W1987998315 hasConceptScore W1987998315C555894677 @default.
- W1987998315 hasConceptScore W1987998315C77176794 @default.
- W1987998315 hasIssue "5" @default.
- W1987998315 hasLocation W19879983151 @default.
- W1987998315 hasOpenAccess W1987998315 @default.
- W1987998315 hasPrimaryLocation W19879983151 @default.
- W1987998315 hasRelatedWork W1983060298 @default.
- W1987998315 hasRelatedWork W1987998315 @default.
- W1987998315 hasRelatedWork W2011041144 @default.
- W1987998315 hasRelatedWork W2016546500 @default.
- W1987998315 hasRelatedWork W2049958758 @default.
- W1987998315 hasRelatedWork W2092560264 @default.
- W1987998315 hasRelatedWork W2123036926 @default.
- W1987998315 hasRelatedWork W4247969395 @default.
- W1987998315 hasRelatedWork W872437002 @default.
- W1987998315 hasRelatedWork W2181878086 @default.
- W1987998315 hasVolume "7" @default.
- W1987998315 isParatext "false" @default.
- W1987998315 isRetracted "false" @default.
- W1987998315 magId "1987998315" @default.
- W1987998315 workType "article" @default.