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- W1988013923 abstract "The synthesis, crystal structure, and spectroscopic characterization of [PPh4]2[(bdt)W(O)(S2)Cu(SC6H4S•)] (3; bdt = benzenedithiolate) relevant to the active site of carbon monoxide dehydrogenase are presented. Curiously, in 3, the copper(I) benzenemonothiolate subcenter possesses a dangling thiyl radical that is stabilized by a disulfido-bridged oxo tungsten dithiolene core. The benzenedithiolate ligand, which is generally bidentate in nature, acts as a bidentate and also as a monodentate in 3. The formation of an unusual dangling thiyl radical has been magnetically and spectroscopically identified and has been supported by the density functional theory level of calculation." @default.
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- W1988013923 date "2011-03-31" @default.
- W1988013923 modified "2023-10-18" @default.
- W1988013923 title "Dangling Thiyl Radical: Stabilized in [PPh4]2[(bdt)WVI(O)(μ-S)2CuI(SC6H4S•)]" @default.
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- W1988013923 doi "https://doi.org/10.1021/ic200258u" @default.
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