FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1988026100> ?p ?o ?g. }

• W1988026100 endingPage "117" @default.
• W1988026100 startingPage "105" @default.
• W1988026100 abstract "The reactions of cadmium halides with the 15-membered macrocyclic crown ethers, 15-crown-5 and benzo-15-crown-5, have been carried out and six new complexes have been isolated and structurally characterized. Metal to ligand stoichiometries of 1:1, 2:1, 3:1 and 3:2 have been observed with a variety of different formulations. Examples of charge separated ion pairs ([(NH4)(benzo-15-crown-5)2]2[Cd2I6]), halogen bridged monomers, dimers or polymers ([Cd(15-crown-5)(OHMe)(μ-Br)CdBr3], [Cd(15-crown-5)(μ-Br)2CdBr(μ-Br)]2(isolated from the same reaction mixture) and [(CdCl2)2CdCl2(15-crown-5)]n), and hydrogen bonded finite chains or polymers ([(Cd(OH2)2(15-crown-5)][CdI3(OH2)]2·2(15-crown-5)·2CH3CN and [CdI2(OH2)2(THF)]·benzo-15-crown-5) have been isolated. Three different types of 15-crown-5 coordination modes have been observed in these complexes. In-cavity coordination resulting in pentagonal bipyramidal geometries about Cd2+ was observed in [(CdCl2)2CdCl2(15-crown-5)]n, [Cd(15-crown-5)(OHMe)(μ-Br)CdBr3], and [Cd(OH2)2(15-crown-5)][CdI3(OH2)]2·2(15-crown-5)·2CH3CN, [Cd(15-crown-5)(μ-Br)2CdBr(μ-Br)]2 displays out-of-cavity coordination with one etheric donor distorted into an axial position of a distorted pentagonal bipyramid. The third coordination mode is secondary sphere coordination via hydrogen bonding which is observed for [Cd(OH2)2(15-crown-5)][CdI3(OH2)]2·2(15-crown-5)·2CH3CN. The good fit of Cd2+ within the cavity of 15-crown-5 results in shorter bonding contacts and a more narrow distribution in CdO values (2.273(7)-2.344(6) Å) than observed for cadmium halide complexes of 18-crown-6 (CdO = 2.69(1)–2.81(1) Å)." @default.
• W1988026100 created "2016-06-24" @default.
• W1988026100 creator A5011469355 @default.
• W1988026100 creator A5062470739 @default.
• W1988026100 date "1996-09-01" @default.
• W1988026100 modified "2023-10-17" @default.
• W1988026100 title "Crown ether mediated cadmium halide dimers and polymers" @default.
• W1988026100 cites W1973989892 @default.
• W1988026100 cites W1977419949 @default.
• W1988026100 cites W1982846170 @default.
• W1988026100 cites W1983271674 @default.
• W1988026100 cites W1983516762 @default.
• W1988026100 cites W1986363084 @default.
• W1988026100 cites W1992001545 @default.
• W1988026100 cites W2000084992 @default.
• W1988026100 cites W2002932513 @default.
• W1988026100 cites W2005901828 @default.
• W1988026100 cites W2010578787 @default.
• W1988026100 cites W2013934255 @default.
• W1988026100 cites W2023422011 @default.
• W1988026100 cites W2034536552 @default.
• W1988026100 cites W2057083222 @default.
• W1988026100 cites W2057315349 @default.
• W1988026100 cites W2062723905 @default.
• W1988026100 cites W2068274661 @default.
• W1988026100 cites W2070326437 @default.
• W1988026100 cites W2081649309 @default.
• W1988026100 cites W2102563132 @default.
• W1988026100 cites W2130041027 @default.
• W1988026100 cites W2134995303 @default.
• W1988026100 cites W2148066840 @default.
• W1988026100 cites W2167590372 @default.
• W1988026100 cites W2406971677 @default.
• W1988026100 cites W35664646 @default.
• W1988026100 doi "https://doi.org/10.1016/s0020-1693(96)05217-6" @default.
• W1988026100 hasPublicationYear "1996" @default.
• W1988026100 type Work @default.
• W1988026100 sameAs 1988026100 @default.
• W1988026100 citedByCount "27" @default.
• W1988026100 countsByYear W19880261002013 @default.
• W1988026100 countsByYear W19880261002014 @default.
• W1988026100 countsByYear W19880261002015 @default.
• W1988026100 countsByYear W19880261002021 @default.
• W1988026100 countsByYear W19880261002022 @default.
• W1988026100 crossrefType "journal-article" @default.
• W1988026100 hasAuthorship W1988026100A5011469355 @default.
• W1988026100 hasAuthorship W1988026100A5062470739 @default.
• W1988026100 hasConcept C111592845 @default.
• W1988026100 hasConcept C115624301 @default.
• W1988026100 hasConcept C116569031 @default.
• W1988026100 hasConcept C145148216 @default.
• W1988026100 hasConcept C158842870 @default.
• W1988026100 hasConcept C159985019 @default.
• W1988026100 hasConcept C170493617 @default.
• W1988026100 hasConcept C171560689 @default.
• W1988026100 hasConcept C178790620 @default.
• W1988026100 hasConcept C179104552 @default.
• W1988026100 hasConcept C185592680 @default.
• W1988026100 hasConcept C188027245 @default.
• W1988026100 hasConcept C192562407 @default.
• W1988026100 hasConcept C2776995031 @default.
• W1988026100 hasConcept C2777255693 @default.
• W1988026100 hasConcept C2778400979 @default.
• W1988026100 hasConcept C32909587 @default.
• W1988026100 hasConcept C544153396 @default.
• W1988026100 hasConcept C55493867 @default.
• W1988026100 hasConcept C71240020 @default.
• W1988026100 hasConcept C8010536 @default.
• W1988026100 hasConceptScore W1988026100C111592845 @default.
• W1988026100 hasConceptScore W1988026100C115624301 @default.
• W1988026100 hasConceptScore W1988026100C116569031 @default.
• W1988026100 hasConceptScore W1988026100C145148216 @default.
• W1988026100 hasConceptScore W1988026100C158842870 @default.
• W1988026100 hasConceptScore W1988026100C159985019 @default.
• W1988026100 hasConceptScore W1988026100C170493617 @default.
• W1988026100 hasConceptScore W1988026100C171560689 @default.
• W1988026100 hasConceptScore W1988026100C178790620 @default.
• W1988026100 hasConceptScore W1988026100C179104552 @default.
• W1988026100 hasConceptScore W1988026100C185592680 @default.
• W1988026100 hasConceptScore W1988026100C188027245 @default.
• W1988026100 hasConceptScore W1988026100C192562407 @default.
• W1988026100 hasConceptScore W1988026100C2776995031 @default.
• W1988026100 hasConceptScore W1988026100C2777255693 @default.
• W1988026100 hasConceptScore W1988026100C2778400979 @default.
• W1988026100 hasConceptScore W1988026100C32909587 @default.
• W1988026100 hasConceptScore W1988026100C544153396 @default.
• W1988026100 hasConceptScore W1988026100C55493867 @default.
• W1988026100 hasConceptScore W1988026100C71240020 @default.
• W1988026100 hasConceptScore W1988026100C8010536 @default.
• W1988026100 hasIssue "1-2" @default.
• W1988026100 hasLocation W19880261001 @default.
• W1988026100 hasOpenAccess W1988026100 @default.
• W1988026100 hasPrimaryLocation W19880261001 @default.
• W1988026100 hasRelatedWork W1965870394 @default.
• W1988026100 hasRelatedWork W1971043130 @default.
• W1988026100 hasRelatedWork W2000832732 @default.
• W1988026100 hasRelatedWork W2022638184 @default.
• W1988026100 hasRelatedWork W2043319102 @default.

• next