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- W1988031112 abstract "Rare earth metals (Ln) are found to act as useful reducing agents for the pinacol coupling reaction of alkyl aryl ketones in the presence of chlorosilanes. Although the hitherto known pinacol coupling reaction using rare earth reducing agents generally exhibits very low diastereoselectivities, the present pinacol coupling by use of a LnR3SiCl system usually indicates higher diastereoselectivities. In particular, a YbMe3SiCl system attains the diastereoselective pinacol coupling of primary alkyl aryl ketones with the dlmeso ratio of 82∼91." @default.
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- W1988031112 date "1999-09-01" @default.
- W1988031112 modified "2023-10-16" @default.
- W1988031112 title "Diastereoselective pinacol coupling of alkyl aryl ketones with rare earth metals in the presence of chlorosilanes" @default.
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- W1988031112 doi "https://doi.org/10.1016/s0040-4039(99)01504-x" @default.
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