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• W1988049779 abstract "The temperature-induced phase transition between the chiral smectic phases, antiferroelectric (smectic-${C}_{A}^{*}$) and ferroelectric (smectic-${C}^{*}$), is found to occur through solitary wave propagation. We measure the free energy, which shows a double well shape in the entire $mathrm{Sm}{C}_{A}^{*}$ temperature range and the global minimum is found to shift from the antiferroelectric order to the ferroelectric order at the transition temperature. However, any significant supercooling is not observed and the transition cannot be described by the first order Landau--de Gennes theory, where the double well potential exists only in a narrow range of temperatures. This implies that the $mathrm{Sm}{C}_{A}^{*}mathrm{text{ensuremath{-}}}mathrm{Sm}{C}^{*}$ transition can occur only nonhomogeneously through the solitary wave propagation which overcomes the high energy barrier between the two minima." @default.
• W1988049779 created "2016-06-24" @default.
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• W1988049779 date "2008-08-28" @default.
• W1988049779 modified "2023-10-16" @default.
• W1988049779 title "Dynamic Mechanism of the Ferroelectric to Antiferroelectric Phase Transition in Chiral Smectic Liquid Crystals" @default.
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• W1988049779 doi "https://doi.org/10.1103/physrevlett.101.097801" @default.
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