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- W1988103615 abstract "Reactions of the meta carboranes 1,7-RR′-1,7-C2B10H10 (R, R′ Me; R Ph, R′ Me; R, R′ Ph; R, R′ 4-FC6H4) with tetrabutylammonium fluoride hydrate (TBAFH) in refluxing tetrahydrofuran gave the corresponding nido-7,9-C2B9H10− salts. The aarboranes and TBAFH also yielded salts of the B-fluorinated anions 10-F-7,9-RR′-7,9-C2B9H9− and 3-F-7,9-RR′-7,9-C2B9H9−. The reaction of 1,7-(4-FC6H4)2-1,7-C2B10H10 with TBAFH monitored by 19F NMR showed cage fluorination occurred during deboronation to give 10-F-7,9-(4-FC6H4)2-7,9-C2B9H9−. The latter anion rearranged spontaneously to 3-F-7,9-(4-FC6H4)2-7,9-C2B9H9− under the reaction conditions. The 11B, 13C, 1H and 19F NMR spectra of the carboranes have been assigned." @default.
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- W1988103615 date "1997-01-01" @default.
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- W1988103615 title "Cage-fluorination during deboronation of meta-carboranes" @default.
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- W1988103615 doi "https://doi.org/10.1016/s0277-5387(96)00520-7" @default.
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