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- W1988105126 abstract "Na 4 3+ and K 4 3+ clusters arrayed in aluminosilicate sodalite are known to show antiferromagnetism below respective Néel temperatures T N =48 and ≃70 K. We newly prepared K–Rb alloy (K 3 Rb) 3+ clusters in addition to Na 4 3+ and K 4 3+ ones, and performed muon-spin relaxation (µSR) measurements. We find a large amplitude of precession signal in zero-field µSR spectra, indicating that antiferromagnetism takes place in the major volume of the samples. The T N is estimated from the temperature dependence of the precession signal to be ≃80 K for (K 3 Rb) 3+ . The internal field at the muon stopping site is estimated from the precession frequency to be ≃92, ≃142, and ≃155 Oe for Na 4 3+ , K 4 3+ , and (K 3 Rb) 3+ , respectively. Therefore, T N and the internal field are found to increase in the increasing order of atomic weight. These results are explained by the increase in the size of the s -electron wave function of clusters and the decrease in their potential depth." @default.
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- W1988105126 date "2010-07-15" @default.
- W1988105126 modified "2023-09-27" @default.
- W1988105126 title "µSR Study on Antiferromagnetism of Alkali-Metal Clusters Incorporated in Zeolite Sodalite" @default.
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- W1988105126 doi "https://doi.org/10.1143/jpsj.79.073707" @default.
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