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- W1988105749 abstract "Inelastic electron tunneling spectroscopy has been used to probe the irreversible chemisorption at 295 K of phenol, catechol, resorcinol and hydroquinone on thin amorphous alumina films in Al/Al2O3/Pb sandwich structure tunneling junctions. This spectroscopy yields a representation of the vibronic excitations of the chemical bonds in the adspecies. Phenol chemisorbs predominantly as C6H5O- on Al+3 sites with a very small amount of associative chemisorption at high coverages. Catechol and resorcinol both adsorb predominently as the di-ion C6H4O2-2, whereas hydroquinone chemisorbs both as the di-ion and as the single ion 1, 4-C6H4(OH)O- at high surface coverages. Hydrogen bonding is observed among the adsorbates and between the adsorbates and the OH groups on the partially hydroxylated Al2O3 surface. The experimental results are explicable in terms of the geometry and chemical properties of the adsorbates and the oxide surface." @default.
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- W1988105749 date "1974-01-01" @default.
- W1988105749 modified "2023-10-03" @default.
- W1988105749 title "Inelastic Electron Tunneling Spectroscopy of Phenol, Catechol, Resorcinol and Hydroquinone Chemisorbed on Alumina" @default.
- W1988105749 doi "https://doi.org/10.7567/jjaps.2s2.863" @default.
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