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- W1988135066 startingPage "507" @default.
- W1988135066 abstract "Several pyridylmethylmetal compounds and their conjugate acids have been prepared. The acid dissociation constants of the pyridinium ions have been measured spectrophotometrically. The results show that the groups CH2Mn(CO)5, CH2Mo(CO)3(π-C5H5), CH2W(CO)3(π-C5H5), and CH2Fe(CO)2(π-C5H5) are extremely strong electron-donating substituents whether in the meta- or para-positions. Approximate σ-values are assigned to these groups and the effects are ascribed to a combination of inductive and hyperconjugative electron donation." @default.
- W1988135066 created "2016-06-24" @default.
- W1988135066 creator A5046616557 @default.
- W1988135066 creator A5051998027 @default.
- W1988135066 date "1970-01-01" @default.
- W1988135066 modified "2023-10-10" @default.
- W1988135066 title "σ-Bonded organotransition-metal ions. Part IX. Strong hyperconjugative and inductive electron donation by some alkyl-manganese, -molybdenum, -tungsten, and -iron carbonyl groups in substituted pyridinium ions" @default.
- W1988135066 doi "https://doi.org/10.1039/j19700000507" @default.
- W1988135066 hasPublicationYear "1970" @default.
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